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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1655-1664 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The electrolyte nonrandom two-liquid model proposed by Chen and Evans provides a thermodynamically consistent framework for representation of the phase equilibria of mixed-solvent electrolyte systems. Using only binary adjustable parameters, the model satisfactorily correlates the vapor-liquid equilibrium and liquid-liquid equilibrium of mixed-solvent electrolyte systems over the entire range of temperature and concentrations.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1781-1790 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method for solving the problem of heat exchanger network synthesis in chemical process plants is presented based on the use of the out-of-kilter algorithm. The method represents an extension of previous approaches based on network flow problem formulations. A new approach to overcome the constraints in forbidden-match problems, termed the dual stream approach, has been developed based on the use of a stream as both a hot and a cold stream. This approach results in considerable savings in utility costs in certain forbidden-match problems. An algorithm to deal with heating or cooling utilities that undergo temperature changes, termed non-point-temperature utilities, is presented using the transshipment model. The new algorithm determines the utility mass flow rates and pinch points accurately.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An electrolyte local composition model is developed for excess Gibbs energy, which is assumed to be the sum of two contributions, one resulting from long range electrostatic forces between ions and the other from short range forces between all the species. The validity of the model is demonstrated for systems emcompassing the entire range from molecular liquid to fused salt.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 251-259 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental and analytical study is reported of transient natural convection in a vertical cylinder. For the experiments a cylinder was partially filled with liquid and subjected to a uniform heat flux at the walls. Thermocouples were used to measure the unsteady temperature field within the liquid; dye tracers were used to study flow patterns. Parameters that were varied included the test liquid (water-glycerin mixtures), the liquid depth, and the wall heat flux. A range of Prandtl number from 2 to 8,000, L/D ratio from 1 to 3, and Grashof number from 103 to 1011 were studied, encompassing both laminar and turbulent flow regimes.An analytical model was developed by dividing the system into three regions: a thin boundary layer rising along the heated walls, a mixing region at the top where the boundary layer discharges and mixes with the upper core fluid, and a main core region which slowly falls in plug flow. The temperature of the core fluid was assumed to vary in the vertical direction but not in the horizontal direction. Natural convection boundary-layer equations were modified to allow for a temperature variation at the outer edge of the boundary layer. The model may be used with a step-by-step computational procedure to predict the temperature distribution in the fluid as a function of time for an arbitrary set of conditions. Results computed by using the model were in good agreement with the experimental data.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 752-753 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 444-454 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The electrolyte nonrandom two-liquid (NRTL) model proposed by Chen et al. (1982) is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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