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  • 1
    Electronic Resource
    Electronic Resource
    Dipotassium carbonate sesquihydrate: rerefinement against new intensity data (2001)
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 57 (2001), S. i94-i97 
    Details
    ISSN: 1600-5368
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The redetermination of the structure of the title compound, K2CO3·1.5H2O, agrees with the results previously reported by Hunter & Jeffrey [J. Chem. Phys (1967), 47, 3297–3302], but with improved precision. The structure is described in terms of the hydrogen-bonding network and the K–O framework, and the C—O bond lengths are compared with those found in other reported alkali carbonate hydrates.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S1600536801016312
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Volatile metal and metalloid species in gases from municipal waste deposits (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 8 (1994), S. 65-69 
    Details
    ISSN: 0268-2605
    Keywords: Waste deposit ; environmental gas ; analysis ; volatile metals ; biogeochemical transfer ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We have detected volatile species of silicon, vanadium, arsenic, bromine, tin, antimony, tellurium, iodine, mercury, lead and bismuth in gases released from domestic waste deposits, using inductively coupled argon plasma mass spectrometry (ICP MS). By concurrent aspiration of a multielement standard solution for calibration, the element concentrations in deposit gas are found to be in the range from 0.1 ng m-3 to 10 μg m-3 gas. The global amount of some metal species emitted by this process may be of the order of several tons per year. These results suggest a biogeochemical pathway for the transfer of metals into the atmosphere via volatile species. This process may have significant influence on atmospheric cycling of metals as well as on metal toxicity within ecosystems.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aoc.590080111
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    The production of methylated organoantimony compounds by Scopulariopsis brevicaulis (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 827-842 
    Details
    ISSN: 0268-2605
    Keywords: Scopulariopsis brevicaulis ; hydride generation ; antimony ; biomethylation ; biotransformation ; solid-phase extraction ; sudden infant death syndrome (SIDS) ; volatile antimony ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cultures of the fungus Scopulariopsis brevicaulis were grown in antimony-rich media. Although volatile compounds of other elements were readily detected in the culture headspace, volatile antimony compounds were formed irreproducibly and at only ultratrace levels. In order to monitor the media for nonvolatile methylantimony compounds, a method of sample preparation was developed, based on solid-phase extraction. This enabled the separation of large quantities of soluble inorganic antimony species from trace amounts of organoantimony compounds before speciation by HG-GC-AAS. By this methodology methylated antimony compounds were detected at concentrations of 0.8- 7.1 µg Sbl-1 in all media in which S. brevicaulis was grown in the presence of antimony(III) compounds. These methylantimony species were not detected in any of the nonliving or medium-only controls. Methylated compounds were not detected where S. brevicaulis was grown in the presence of antimony(V) compounds. This is the first study to show that antimony(III) compounds are biomethylated by S. brevicaulis under aerobic-only growth conditions. Copyright © 1998 John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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