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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 1853-1860 
    ISSN: 0887-6266
    Keywords: nylon-6 ; water sorption ; sorption isotherm ; thermally stimulated depolarization currents ; thermal sampling ; dielectric relaxation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of water on the low temperature dielectric relaxations of nylon-6 has been investigated in the range from dry to water-saturated polymer by means of sorption experiments and thermally stimulated depolarization currents (TSDC). Three different ranges of water sorption are observed and their reflection in the TSDC spectra is examined. It is found that position and intensity of the TSDC maxima exhibit characteristic and different behavior in each of these sorption ranges. The critical concentrations are 1.5 ± 0.5% and 6.0 ± 0.5% water content. An interpretation of the experimental results is given with respect to the molecular origins of the low-temperature dielectric relaxations and the mechanisms of water sorption in nylons. The most important idea is that water exists as firmly bound, loosely bound, and clustered water, depending on its concentration. An attempt is made to determine relations between these different states of water in nylon-6 and some characteristic features of the low-temperature TSDC spectrum. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 31 (1980), S. 767-770 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: TSD-spectra are measured after thermal and optical excitation at several values of polarizing field strength and intensity of light. An α-relaxation region is not evident by optical excitation. The β-relaxation region is observable, but it is superimposed by another relaxation region for greater polarizing field strength. By optical excitation further maxima are observed at temperatures higher than the temperature of the β-relaxation. They are interpreted by a trap mechanism. An identical space charge maximum exists for both the excitation processes.
    Notes: TSD-Spektren wurden nach thermischer und optischer Anregung bei verschiedenen Werten von Polarisationsfeldstärke und Quantenflußdichte gemessen und miteinander verglichen. Bei optischer Anregung ist keine α-Relaxation nachweisbar, das β-Relaxationsgebiet dagegen tritt auf, wird aber insbesondere bei höheren Polarisationsfeldstärken von einem weiteren Relaxationsgebiet teilweise überlagert. An das β-Relaxationsgebiet schließen bei optischer Anregung zu höheren Temperaturen hin Maxima an, die durch Haftstellenmechanismen interpretiert werden. Bei beiden Anregungsarten existiert ein identisches Raumladungsmaximum.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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