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  • 1
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract An investigation was made into an illness episode characterized by cholinesterase depression and cholinergic symptoms reported among 118 field workers harvesting grapes treated with Torak® (dialifor) and Zolone® (phosalone) in a vineyard near Madera, California. Dialifor had been applied at the rate of 1.0 pound per acre in 30 gallons of water between 15 and 40 days earlier using a Kinkelder air blast sprayer. Dissipation studies in an earlier study in Soledad, California, using concentrated spray resulted in initial dislodgeable residues of 2.1 ug/cm2 with a half-life of 14 to 15 days. A similar level of dislodgeable residue resulted at the time of application in the vineyard at Madera. Dislodgeable residues as high as 0.7 ug/cm2 were encountered by workers at the time of entry with most residues being in the range of 0.11 to 0.45 ug/cm2. Residue of dialifor on the foliage in 36 other grape vineyards in the San Joaquin Valley were determined at the time of harvest and were shown to be 0.13 ug/cm2 or less. In four of the 36 vineyards, blood was obtained from workers harvesting grapes. None of the field workers had blood cholinesterase values outside control values. The investigation indicated that with initial dislodgeable residues of dialifor as high as 2.3 ug/cm2, a period of at least 65 days is required before a possibly safe level of something less than 0.06 ug/cm2 is reached. The analysis of the residues in the 36 other vineyards indicated that the initial deposits and/ or the half-life of dialifor varied considerably throughout the San Joaquin Valley. Because of this variation, the use of reentry intervals for dialifor may require replacement by on-site residue tests prior to entry. The results indicated that phosalone residues were not responsible for the illness in the field workers.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Archives of environmental contamination and toxicology 9 (1980), S. 217-229 
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract The effectiveness of currently used pesticide mixing-loading and application equipment in preventing workers from being exposed to cholinesterase (ChE) inhibiting pesticides was measured. Blood samples from workers involved in the application of pesticides in Monterey and Imperial counties of California were analyzed for ChE activity. The analyses indicated that only the mean red cell activity of mixer-loaders was significantly less than controls. Seasonal variations in ChE activity were noted for workers in Imperial County between January and August. These variations were apparently related to the toxicity of the pesticides used. A prototype, closed-transfer system used in Imperial County did not substantially reduce pesticide residues in the air around mixing-loading sites or prevent a reduction in ChE activity over that of open-transfer systems. This was attributed to inadequate training in the use of the new equipment on the part of the mixer-loaders and improperly maintained equipment. A prototype closed-transfer system used in Monterey County appeared to give some protection to mixer-loader applicators during the application season; however, the blood ChE activities of two mixer-loaders using another prototype closed system in Monterey County were severely depressed.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract Blood cholinesterase (CHE) activities and urinary dialkyl phosphate levels of five mixer-loaders and four mixer-loader applicators, using a closed-transfer system in conjunction with mixing-loading and application equipment, were monitored over a period of 18 weeks. Airborne pesticide residues in the breathing zone during mixing-loading and the transfer of concentrated liquid pesticide from their original container to mix and spray tanks were determined along with airborne residues during ground application. Blood ChE activities of the majority of the workers increased slightly during the study with increased use of toxic organophosphates and carbamates. Urinary dialkyl phosphate levels varied between 0.02 and 2.4 ppm. During the study, the blood ChE activities of two mixer-loaders decreased and dialkyl phosphate levels of 2.4 ppm were found in the urine of one worker. An investigation indicated that the workers had failed to use the provided closed-transfer system. Airborne residues from liquid pesticides during closed transfer and mixing-loading averaged 5.8μg/m3, while residues from dusty powders averaged 152μg/m3. Airborne residues during ground application averaged 3.7μ/m3 during the workday. Mevinphos residues on cloth patches averaged 0.2μg/cm2.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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