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  • 1
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 314 (July 2006), p. 95-100 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Cerel has devoted the past several years to the development of prototype microcomponentsfor the electronics industry based on EPD processing. The present contributionsummarizes some problems Cerel has experienced in the integration of EPD for metallic silverparticles into a viable production process. In particular, the parameters that need to be controlleddue to the metallic nature of the silver particles have been analyzed.Selection of a metallic silver powder suitable for EPD is the key factor. An appropriate particle sizeand shape, as well as a controlled size distribution, significantly improves the green density of thedeposit. Metallic silver particles in a suspension tend to aggregate, especially when exposed to anelectric field. This leads to premature sedimentation, as well as low green densities for theelectrophoretic deposit. The following factors were found to contribute significantly to preventingpremature sedimentation:• The replacement of pure silver by palladium-coated silver particles.• Dispersion preparation in a high viscosity medium of low dielectric constant.• The presence of steric, electrosteric and ceramic oxide additives in the siver powderdispersion.Finally, control of the solids loading and particle size distribution in the suspension, and thegeometrical design of the EPD cell, including the counter-electrodes, were also shown to beimportant for the successful electrophoretic deposition of silver particles in the commercialproduction of micro-components by EPD
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 12 (1978), S. 1-12 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The rotating ring-disk electrode technique has been applied to the study of anodic dissolution of dental amalgam in a simulated saline solution.The electroactive domains of the silver, tin, and mercury couples (the main constituents of the amalgam) were determined from current-potential curves obtained at a rotating gold-disk electrode in solutions containing salts of the respective metals. Subsequently, anodic currents were applied to a rotating amalgam-disk electrode and the soluble products produced were identified using a concentric gold ring electrode, i.e., using the rotating gold-ring, amalgam-disk electrode. Species generated at the amalgam disk are transferred to the gold ring by convective diffusion. Tin ions were found to be the only soluble species generated at the amalgam disk. No evidence for dissolution of other components was found. The selective dissolution of tin from the amalgam is also consistant with potential shifts observed in repetitive current-potential curves of an amalgam disk.This study provides a direct proof for the selective dissolution of tin during corrosion of dental amalgam in an in vitro environment.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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