Library

Notes: A two-dimensional, field scale, finite-element ground water model was developed to simulate the ground water discharge process within an unconfined coastal aquifer. Model development was based on the density dependent fluid flow approach with water table and dynamic tidal boundary conditions. The performance of the model was compared against data collected from the Columbia Aquifer on the eastern shore of Virginia. The dynamic tidal boundary conditions were necessary to reproduce the surficial mixing zone observed within the ground water intertidal zone of the aquifer. The model was able to reproduce field data on the movement of the near-shore water table, ground water salt concentrations, and ground water discharge rates and patterns. The model was not able to replicate the short-term fluctuation in salt concentration observed within the surficial mixing zone. The inability to account for the wave action of the tides within the intertidal zone is believed to be responsible for this difficulty. The development of the model provided a new method to investigate ground water discharge to coastal systems.

Notes: : Surface water, groundwater, and groundwater discharge quality surveys were conducted in Cherrystone Inlet, on Virginia's Eastern Shore. Shallow groundwater below agricultural fields had nitrate concentrations significantly higher than inlet surface waters and shallow groundwater underlying forested land. This elevated nitrate groundwater discharged to adjacent surface waters. Nearshore discharge rates of water across the sediment-water interface ranged from 0.02 to 3.69 liters·m−2·hr−1 during the surveys. The discharge was greatest nearshore at low tide periods, and decreased markedly with increasing distance offshore. Vertical hydraulic heads, Eh, and inorganic nitrogen flux in the sediments followed similar patterns. Nitrate was the predominant nitrogen species discharged nearshore adjacent to agricultural land use, changing to ammonium farther offshore. Sediment nitrogen fluxes were sufficient to cause observable impacts on surface water quality; nitrate concentrations were up to 20 times greater in areas of groundwater discharge than in the main stem inlet water. Based on DIN:DIP ratios, nitrogen contributions from direct groundwater discharge and tidal creek inputs appear to be of significant ecological importance. This groundwater discharge links land use activity and the quality of surface water, and therefore must be considered in selection of best management practices and water quality management strategies.

Notes: This research investigated the transport of land-applied nutrients and pesticides from unconfined aquifers to tidal surface waters of Virginia's coastal plain. Ground water, estuarine surface water, ground water discharge, upland soil, and offshore sediment samples were collected from May 1992 until February 1993 from four agricultural sites. Samples were analyzed for inorganic nitrogen and phosphorus and five pesticides: atrazine, cyanazine, alachlor, metolachlor, and carbofuran. Pesticides from aqueous samples were determined by liquid-solid phase extraction followed by gas chromatography-electron capture detection (GC-ECD) and/or by pesticide-specific immunoassay. Soil and sediment samples were analyzed by extraction and gas chromatography/mass spectrometry (GC/MS). Nutrient measurements indicated that fertilizer nitrogen was moving from the ground water to the surface water, and nitrogen fluxes across the sediment-water interface were correlated with fresh water discharge rates. Mean nitrate-N flux was 2.48 mg/m2hr, with a maximum value of 30.98 mg/m2hr. Pesticides were detected in more than half of the upland soil samples, in approximately 40 percent of the ground water samples, and in just under 20 percent of the seepage meter samples. Pesticides were not detected in any of the offshore sediment samples or surface water samples. Alachlor and metolachlor were detected in upland soil samples at concentrations ranging from 10 to almost 500 μg/kg. All five pesticides were found in ground water samples at concentrations generally below 1 μg/L, with alachlor, atrazine, and metolachlor most frequently found. Alachlor, atrazine, cyanazine, and metolachlor were detected in water discharging across the sediment-water interface and entering estuarine waters at concentrations ranging from 0.05 to 0.5 μg/L. These levels were generally consistent with the amount of dilution due to the mixing of fresh ground water and saline pore waters prior to discharge across the sediment-water interface. Based on all positive detections of pesticides in ground water discharge, which represented approximately 18 percent of all samples, average flux rates of cyanazine, metolachlor, alachlor, and atrazine were 0.32, 0.37, 0.80, and 1.12 μg/m2hr, respectively. These findings indicate that submarine ground water transport of both nutrients and pesticides does occur, and this transport route should be considered when implementing agricultural management practices. The levels of nitrogen transport to surface water appears significant. The overall levels of pesticide movement through ground water, although generally quite low, represent a transport route that is commonly neglected in watershed management.

Notes: : Inputs of copper-based crop protectants from tomato fields grown under plastic mulch agriculture (plasticulture) to an estuarine creek were investigated. Copper was measured in runoff from diverse land-uses including conventional agriculture, plasticulture, residences, and natural areas. Water column and sediment copper concentrations were measured in plasticulture and control (nonagriculture) watersheds. Copper concentrations in plasticulture-impacted creeks exceeded background levels episodically. High concentrations occurred during or immediately after runoff-producing rains. Concentrations of 263 μg/L total copper and 126 μg/L dissolved copper were measured in a tidal creek affected by plasticulture; concentrations exceeded the shellfish LC50 values and the water quality criteria of 2.9 μg/L dissolved copper. Control watersheds indicated background water column levels of ≤ 4 μg/L dissolved copper with similar copper levels during periods with and without rain. The copper concentrations in tomato plasticulture field runoff itself contained up to 238 μg/L dissolved copper. Copper concentrations in runoff from other land-uses were less than 5 μg/L dissolved copper. Creek sediment samples adjacent to a plasticulture field contained significantly higher copper concentrations than sediments taken from nonplasticulture watersheds.