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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Soil use and management 14 (1998), S. 0 
    ISSN: 1475-2743
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract. Emissions of ammonia (NH3) and nitrous oxide (N2O), and nitrate (NO-3) leaching were measured in two field experiments following application of pig slurry at rates corresponding to 83–96 kg NH4-N ha-1 before sowing. In spring and in autumn 1994, slurry was applied by four methods: trenching (T), shallow injection (S), band spreading immediately followed by harrowing (B/H) and band spreading (B). NH3 emission measurements were made during the first week after application in both experiments. In the spring experiment N2O emissions and NO-3 leaching were measured during 6 and 52 weeks after spreading respectively, and during 11 and 33 weeks after spreading in the autumn experiment. In spring, the increased N2O emissions (i.e. control subtracted) ranged from 0.27% (T) to 0.45% (B/H), and in the autumn study from 0.92% (T) to 1.14% (B/H), of applied NH4-N, although showing no statistically significant differences. In order to validate the chamber measurements, a ‘megachamber’(21 m2) was used together with an infrared spectrometer. The emissions agreed well for (B/H), while (B) resulted in lower emissions compared with the smaller chambers. Emissions of NH3 were about one order of magnitude higher. In spring, (B) gave the highest emission, reaching 19.5% of applied NH4-N, whereas (S), and (B/H) gave the lowest emissions, reaching 1.2 and 3.5% of applied NH4-N, respectively. NH3 emissions in autumn were 15–20% lower compared with spring. In spring the increased nitrate leaching ranged from 10.1 (T) to 24.9 kg ha-1 (B/H) and from 29.5 (B) to 37.8 kg ha-1 (T) in the autumn experiment, showing no statistically significant differences. Estimations of indirect N2O emissions due to ammonia deposition and nitrate leaching, suggested that the N2O contribution from NH3 deposition was relatively small, while the indirect N2O emissions from NO-3 leaching were of the same order of magnitude or higher than the direct N2O emissions.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Chromatography A 279 (1983), S. 643-648 
    ISSN: 0021-9673
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 423 (2003), S. 273-276 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The emission of volcanic gases usually precedes eruptive activity, providing both a warning signal and an indication of the nature of the lava soon to be erupted. Additionally, volcanic emissions are a significant source of gases and particles to the atmosphere, influencing tropospheric and ...
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-0662
    Keywords: Airborne and groundbased FTIR spectroscopy ; heterogeneous chemistry ; chlorine reservoirs ; chlorine activation ; filamentation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract In the winter of 1994/95 the German Transall research aircraft performed 5 campaigns in the European Arctic with 22 flights altogether. An extensive dataset of HNO3, ClONO2 and O3 column amounts was obtained by MIPAS-FT (Michelson Interferometer for Passive Atmospheric Sounding - Flugzeug Transall) onboard the aircraft. In this paper we present the variability of the ClONO2 reservoir gas in the course of the winter. We include groundbased FTIR measurements of HF, HCl and ClONO2 to discuss the airborne observations with regard to the partitioning of inorganic chlorine. From mid-December until the end of January, MIPAS measured a stable ClONO2 collar with constantly low column amounts inside the polar vortex and maxima at the edge. This observation reflected widespread conversion of ClONO2 to reactive chlorine inside the vortex for at least six weeks. In good accordance, the ground stations measured low in-vortex HCl and ClONO2 column amounts and conversion of HCl into ClONO2 in the region of the ClONO2 maxima. In the first week of February the ClONO2 amounts started to increase in the edge region as well as inside the vortex. Between March 21 and 27, just one week after the last cold period, MIPAS observed exclusively high ClONO2 column amounts inside the vortex, indicating fast deactivation of active chlorine. In the same period the ground stations measured an excess of ClONO2 over HCl. Further, the high ClONO2 implies that the polar vortex was renoxified in March. Lower ClONO2 values, observed inside the vortex on the flights of April 5 and 8, and an increased HCl/ClONO2 ratio, measured from ground, marked the starting redistribution within the chlorine reservoir species to the photochemically more stable HCl. In February, March and April, MIPAS observed mixing of ClONO2-rich air masses with midlatitude air at the vortex edge. A very clear event happened on March 27. On this flight a distinct ClONO2 minimum was measured at the vortex edge, which was closely correlated with a filament of midlatitude air observed by OLEX (Ozone Lidar EXperiment) onboard the Transall.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1573-0662
    Keywords: SESAME ; polar vortex ; arctic stratosphere ; ground based FTIR ; hydrogen fluoride ; hydrogen chloride ; nitric acid ; chlorine nitrate ; nitrous oxide ; chlorine monoxide ; carbonyl fluoride ; 3D-Model ; photochemical trajectory model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Vertical columns of HF, HCl, HNO3, ClONO2, N2O, ClO and COF2 were measured at Harestua, Norway (60.22° N, 10.75° E, Elevation 600 a.s.l.) beginning on 24′ November 1994 and concluding on 1′ May 1995 during Phase-III of the SESAME (Second European Stratospheric Arctic and Mid-latitude Experiment) measurement campaign. The vertical columns of HCl, HNO3 and ClONO2 measured on 81 days were compared with columns calculated by the 3-D Cambridge model SLIMCAT. In addition the results were also interpreted by comparison with a photochemical trajectory model. Good agreement was seen for HCl while the nitrogen compounds showed larger discrepancies, especially for ClONO2. Evidence for chlorine activation was seen with 65% reduction of the chlorine reservoirs (HCl + ClONO2) while the levels of ClO were greatly enhanced. Interpretation of the loss with the trajectory model indicated condensation of chlorine on PSCs. The vertical column ratio of COF2 and HF was measured to 0.21 outside the vortex and a factor of two lower inside. The recovery of ClONO2 was seen to be much faster than that of HCl in the early spring.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1573-0662
    Keywords: NO2 ; O3 ; SO2 ; intercomparison ; differential optical absorption spectroscopy (DOAS) ; troposphere
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The results of an intercomparison campaign of eight different long path UV-visible DOAS instruments measuring NO2, O3 and SO2 concentrations in a moderately polluted urban site are presented. For effective optical path lengths of 230 and 780 m the overall spread of these measurements (±1σ) are 5×1010, 6×1010 and 1×1010 molec·cm-3 (2.0, 2.4, and 0.4 ppb) for these molecules respectively when all instruments used a common set of absorption cross sections. The remaining differences are not completely random and the systematic differences are attributed to the different retrieval methods used for each instrument.
    Type of Medium: Electronic Resource
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