ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The photo-induced formation of ketonic and phenolic isomers from O-acetyl-1-dehydro-testosterone (1a) and from its 4-methyl homologue 1d in dioxane solution has been described earlier [8][9][13]. The present paper summarizes the findings which resulted in the course of further investigations, and which, in part, have been published in preliminary form [11][14] and in recent reviews [12]. This work includes the ultraviolet irradiation of dienone 1a, its 10α-stereoisomer 2a, and its 1-, 2- and 4-methyl homologues 1b-d. A series of rearrangements occurred in each case, as shown in Charts 2, 3, and 19.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19660490306
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