ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The infrared and Raman spectra of perchlorinated phthalocyanine (Pc), H2PcCl16, LuPc2Cl32 and the unsymmetrical LuPc2Cl16 are reported. The vibrational data set also include SERRS and the far-infrared spectra between 100 and 400 cm-1. The vibrational assignment of characteristic wavenumbers was supported by a semi-empirical calculation using the PM3 Hamiltonian. The H2Pc molecule was used as a reference in the PM3 vibrational calculations. The effect of the chlorine substituents on the optical spectra of the phthalocyanine ring is examined.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250241213
Permalink