ISSN:
0887-624X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The acetylation of linalool with acetic anhydride was carried out in the presence of polystyrene-bound aminopyridines and triethylamine. The catalytic activity of the immobilized aminopyridines increased with decreasing percentage of ring substitution and with increasing spacer-chain length. The increased activity is attributed to an increase in the amount of aminopyridine units complexed with acetic anhydride. The acetylation could be successfully conducted by use of a mixture of the immobilized aminopyridines and polymer-supported benzyldiethylamine, which effectively trapped acetic acid formed in the reaction system.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1987.080250108
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