ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The 2-phosphaindolizines 1 react with hydrogen sulfide and elemental sulfur to give the new zwitterionic heterocyclic systems 2 of the N-pyridiniomethyl dithiophosphinate type. In contrast, no reaction is observed with sulfur alone. MeI methylates 2e,f at sulfur. The analogous pyridiniodiselenophosphinate 5 results from the reaction of 1a with 1,3,2,4-diselenadiphosphetane-2,4-diselenide, 4a, in the absence of an additional base. As a further product, the perselenophosphinic anhydride 6 is identified. In the presence of triethylamine, 1a reacts with each of the diselenides 4a-c to give the new triethylammonium diselenophosphinates 7a-c, respectively. This reaction can be extended to 1-aza-2-phosphaindolizine, 8, which yields with each of 4a,b and NEt3 the diselenophosphinates 9a,b, respectively. The anhydride 6 and the diselenophosphinates 7 and 9 result from an electrophilic substitution at the phosphaindolizine ring. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9:445-452, 1998
Additional Material:
6 Tab.
Type of Medium:
Electronic Resource
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