ISSN:
0018-019X
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
A method is described in which the ‘allowed’ course of a reaction is determined by means of an analysis - within the symmetry point group common to reactants and products - of their molecular orbitals and of the distortions that occur along the reaction path connecting them. The procedure, and its relation to and advantages over conventional correlation methods, is illustrated with a few very well known reactions: Cyclization of hexatriene, the ‘photochemical Diels-Alder reaction’ and the stepwise and concerted [2+2]-cycloadditions.
Zusätzliches Material:
9 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/hlca.19750580726
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