ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Organoiron thio- and seleno-terephthaloyl chloride complexes CpFe(CO)2ECO(C6H4)COCl (E = S and Se) react with NaOH and NaNH2 to give quantitative yields of the acid Cp(CO)2ECO(C6H4)CO2H and the amide CpFe(CO)2ECO(C6H4)CONH2 respectively. These amide and acid derivatives react with the terephthaloyl chloride complexes to give a new series of imide-bridged [CpFe(CO)2ECO(C6H4)CO]2NH and anhydride-bridged [CpFe(CO)2ECO(C6H4)CO]2O organoiron dinuclear homo and hetero dichalcogeno terephthalate complexes. The complexes were characterized by elemental analysis, i.r. and 1H-n.m.r. spectra.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1007034330387
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