ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
The Reaction of Boron-Nitrogen Compounds with Excited Carbon Atoms Generated in an ArcThe interaction of carbon vapor from a carbon are with dimethylaminoborane, (CH3)2N—BH2 (1), yields as the main reaction product (dimethylamino)methylborane, (CH3)2 N—BH—CH3 (3), which combines with the starting material to form the four-membered ring compound 5. Other compounds formed in this reaction are (dimethylamino)dimethylborane, (CH3)2N—B(CH3)2 (2), and dimethylaminborane, (CH3)2NH—BH3, as well as the previously unknown compound (CH3)2N—BH—O—BH—N(CH3)2 (6), which could be isolated.
Notes:
Die Reaktion von im Lichtbogen erzeugten Kohlenstoffatomen mit Dimethylaminoboran, (CH3)2N—BH2 (1), ergibt als Hauptreaktionsprodukt das Dimethylamino-methylboran, (CH3)2N—BH—CH3 (3), das sich mit dem Ausgangsmaterial zur Vierringverbindung 5 umsetzt. Weiterhin findet man Dimethylamino-dimethylboran, (CH3)2N—B(CH3)2 (2) und Dimethylamin-boran, (CH3)2NH—BH3. Schließlich kann die bisher noch nicht bekannte Verbindung (CH3)2N—BH—O—BH—N(CH3)2 (6) isoliert werden.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19711040219
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