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  • 1
    ISSN: 1572-879X
    Keywords: selective oxidation ; molybdates ; vanadates ; acrolein ; acrylic acid ; temperature‐programmed methods ; concentration‐programmed methods
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The mode of action of the oxidation‐active centres in Mo–V mixed oxides on the selective oxidation of an unsaturated aldehyde was investigated by non‐steady‐state methods. Various oxidation‐active centres, differing in activity and selectivity, were identified by non‐steady‐state methods. In addition, the influence of the crystallinity of the Mo–V mixed oxides on the activity and selectivity properties were investigated. It was shown that, in contrast to crystalline samples, only X‐ray‐amorphous Mo–V mixed oxides contained selective oxidation centres. The measurements were used to derive a model based on the interaction of active centres with various redox properties.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 94 (1982), S. 263-274 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ferrimagnetische hexagonale Ferrite sind aufgrund ihrer besonderen kristallographischen Eigenschaften den herkömmlichen Magnetpigmenten in der Koerzitivfeldstärke weit überlegen. Sie erscheinen daher geeignet für teilweise neue und in der Entwicklung befindliche magnetische Informationsspeicherverfahren. So könnten hochkoerzitive Magnetbänder mit Bariumferrit als Masterbänder zum Kopieren von magnetischen Informationen oder zur Herstellung fälschungssicherer Magnetkarten verwendet werden, wenn es gelänge, Magnetköpfe mit höheren Schreibfeldern zu entwickeln. Weiterhin sind plättchenförmige hexagonale Ferritpigmente mit senkrecht zur Plättchenebene orientierter magnetischer Vorzugsrichtung für eine magnetische Senkrechtaufzeichnung von großem Interesse. In diesem Fortschrittsbericht werden der kristallographische Aufbau und der Magnetismus der hexagonalen Ferrite sowie chemische Verfahren zu ihrer Herstellung diskutiert. Besonders Reaktionen in Salzschmelzen oder unter hydrothermalen Bedingungen führen zu feinteiligen Pigmenten mit einem ausgeprägt hexagonalen, plöttchenförmigen Teilchenhabitus, einem engen Teilchengrößenspektrum und vorteilhaften magnetischen Eigenschaften. Durch Austausch der Kationen lassen sich die magnetischen Eigenschaften der aus Salzschmelzen kristallisierten Pigmente einstellen.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 21 (1982), S. 270-282 
    ISSN: 0570-0833
    Keywords: Hexagonal ferrites ; Ferrites ; Magnetic recording materials ; Information storage procedures ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Owing to their particular crystallographic properties, ferrimagnetic hexagonal ferrites exhibit a far greater coercive force than the conventional magnetic pigments. They therefore appear to be suitable for use in magnetic information storage procedures, some of which are novel and are at the development stage. Thus, magnetic tapes of high coercive force containing barium ferrite could be used as master tapes for copying magnetic information or for producing forgery-proof magnetic cards, if magnetic heads having high-order write fields were successfully developed. Moreover, platelet-like ferrite pigments in which the preferred direction of magnetic orientation is perpendicular to the plane of the platelet are of great interest for perpendicular magnetic recording.In this progress report, the crystal structures, magnetic characteristics of hexagonal ferrites, and chemical processes for their production are discussed. In particular, reactions in salt melts or under hydrothermal conditions produce finely divided pigments whose particles have a pronounced hexagonal, plate-like habit, a narrow particle size distribution, and advantageous magnetic properties. The magnetic properties of the pigments crystallized from salt melts may be adjusted by cation exchange.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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