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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 727-741 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new discretization procedure for the agglomeration equation is presented. The intrinsic problems caused by discretization of the particle-size distribution are mitigated by using proper probability functions. Thus, the new discretized equation predicts the same total number of particles as its continuous counterpart and guarantees conservation of mass. This general method can correctly predict any two properties simultaneously and is not limited to number and mass. Simulation results with various agglomeration kernels show that the new method provides significant improvements over the conventional discretization method. Furthermore, the new method allows the user to choose equal-size intervals or geometric-size intervals with any geometric ratio to cover the particle-size range. In addition to flexibility, the latter feature leads to better accuracy in particle-size distribution predictions.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 1204-1216 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new discretization method, applicable for both batch and continuous systems, is developed for the breakage equation. The problem of intrainterval interactions due to discretization is accounted for by matching the zeroth and first moments of the continuous population balance equation with the corresponding moments of the discretized equation, thereby guaranteeing conservation of mass and total number of particles. Without loss of generality, the use of this method is demonstrated with a power law form of the specific rate of breakage, and with both theoretical and empirical breakage functions. The systematic method requires minimum computational efforts by allowing the user to choose either geometric size intervals with any geometric ratio or equal-size intervals for the particle size range. Simulation results show that the new method significantly improves predictions of the particle size distribution over the discretization method currently in use.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 715-726 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A prototype computer program SOLIDS has been developed for the simulation of processes with solids processing steps. In addition to heat and mass balances, the equipment units are modeled with discretized population balance equations. Any transformation mechanisms for the particle-size distribution (PSD) - nucleation, growth, dissolution, agglomeration, and breakage - can be represented. With the sequential modular code, the PSD can be tracked from unit to unit in a complete plant. To provide maximum flexibility for further development, new or improved equipment models and discretization techniques can be included as additional subroutines. Case studies show that accounting for the PSD can lead to improved equipment design and a more complete description of the interactions among the units in the plant.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1600-1611 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method for generating theoretical breakage distribution functions for multiple particle breakage is presented. It starts with the joint probability function that accounts for all the child particles; it is then reduced to the marginal probability function commonly used in the breakage equation. This method is flexible enough to allow the user to choose the number of child particles and the functional form to be used. The method is demonstrated with both product and summation functions with a power-law form. To facilitate the use of these theoretical functions for statistical analyses, a companion discretized breakage equation is developed. The new equation guarantees the conservation of mass and correct prediction of the total number of particles despite discretization. It is easy to use because it is a set of ordinary differential equations and applicable to both equal-size and geometric-size intervals. Simulation results show that different breakage distribution functions coupled with different breakage rates can produce almost indistinguishable particle-size distributions, signifying the need for further work in this area.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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