ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
During the synthesis of a series of square-planar [TeCl2(stu)2] complexes, where stu represents bulky di- or tetrasubstituted thioureas, the title compound, [TeCl{(C6H11NH)2CS}3]Cl or C39H72ClN6S3Te+·Cl−, was the unexpected result when stu was N,N′-dicyclohexylthiourea. The complex is square planar, with Te—S distances of 2.5803 (4), 2.6211 (4) and 2.8214 (4) Å, and a Te—Cl distance of 2.6485 (4) Å, indicating a small trans influence of the thiourea ligand.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S010827010100659X
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