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Some aspects of the polymerization of n-butyl vinyl ether by chromyl chloride (1979)

Biswas, Mukul ; Kabir, G. M. Ahsanul

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 673-681

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The rate of n-butyl vinyl ether polymerization by chromyl chloride is first order in [catalyst] and second order in [monomer]. Added H2O (after a certain concentration) and HCl increase the rate, thiophene retards the rate, while pyridine inhibits the rate. DP is independent of [chromyl chloride] and increases with increasing [monomer] up to 1M, thereafter becoming independent of it. Both rate and DP increase over the range 10-32°C and decrease at higher temperatures.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1979.170170306

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