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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 283-292 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrodynamics of a pilot plant multistage mixer column extractor was studied for the toluene/water physically equilibrated system. The effects of rotational speed, and continuous and dispersed phase flow rates were investigated under a variety of operating conditions. Dispersed phase axial holdup profiles, determined by a noninvasive ultrasonic method, showed a strong nonuniformity. Depending on the operating conditons, holdup profiles can change from a concave shape to a sigmoidal form with a maximum in the bottom of the column. Sauter mean diameter and drop size distribution profiles are strongly affected by rotational speed. Significant, but weaker, are the effects of continuous and dispersed phase flow rates. Continuous monitoring of the holdup profile in the proximity of flooding leads to the formulation of proper criteria for the prediction of flooding. These criteria are appropriate for models allowing for axial variation of the holdup along the contactor.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 407-418 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A population-balance-equation model is employed for the analysis of liquid-liquid extraction columns. This model considers drop breakage, coalescence, and exit phenomena for the drop phase caused by drop-drop and drop-continuous phase interactions. Drop breakage and coalescence rates are employed from a previous study on liquid dispersions in stirred-tank contactors. A drop exit frequency is developed based on a stochastic modeling approach. The model is tested by drop size distribution and dispersed-phase volume fraction (holdup) data obtained for a multistage column contactor of pilot-plant scale. Steady-state drop size distribution and transient holdup measurements are obtained by a photomicrographic technique and an ultrasonic technique, respectively. The model can predict flooding of the column. The effect of mass transfer on the hydrodynamic parameters of the contactor is also examined. The population-balance-equation model can be used for the control of extraction columns and can be extended to include mass-transfer calculations for the prediction of extraction efficiency.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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