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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 3857-3866 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present the theoretical analysis of the quasistatic capacitance of metal–insulator–semiconductor structures for the case of amorphous semiconductors. The contribution of the bulk of the semiconductor is emphasized. We show that the semiconductor bulk capacitance is simply given by the ratio, taken at the insulator/semiconductor interface, of the space-charge density to the electric field. From the explicit expressions of these quantities as a function of the surface potential, a numerical calculation of the capacitance versus bias curves is performed. This is used to discuss the ability of the capacitance to reproduce the underlying structures of the density of states (DOS) in the gap. We derive also approximate analytical expressions of this capacitance in the case of exponentially distributed band-tail states. Moreover, we show that it is possible to reconstruct the DOS of the amorphous semiconductor from the bias dependence of the semiconductor capacitance using simple approximate analytical expressions. In particular, the square of the bulk semiconductor capacitance can lead in most cases to a reasonable DOS reconstruction. Using the capacitance versus bias curves derived from the numerical simulation, the accuracy of the reconstruction is then checked on DOS examples consisting of two exponential band tails and a Gaussian deep defect density, which can be representative of typical amorphous semiconductors such as hydrogenated amorphous silicon (a-Si:H). We emphasize the influence on the deep gap states reconstruction of the bulk Fermi-level position, whether it is located in a DOS minimum or not. We also discuss the influence of the characteristic temperature in the case of an exponential band tail which should be met in the accumulation bias regime. As this was done in the crystalline case to develop the metal–oxide–semiconductor technology, the method proposed can be used as a characterization tool to investigate metastability phenomena and to optimize technological processes related to amorphous semiconductor field-effect devices. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 317-320 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The metastability of the electronic properties of hydrogenated amorphous silicon (a-Si:H) films deposited at high rates by the rf glow discharge decomposition of mixtures containing 40% silane in helium is compared with that of device quality a-Si:H material deposited at 250 °C under standard low deposition rate conditions. The density of states above the Fermi level of the films obtained under helium dilution decreases for deposition temperatures increasing from 250 to 350 °C, both after annealing and after light soaking. At 350 °C, the density of states becomes comparable in both states to that of device quality low deposition rate a-Si:H. We observe a correlation between these results and the degradation of the photoconductivity and the below-Fermi-level defect density measured in situ during light soaking. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 4727-4731 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The modulated photocurrent technique performed under different illumination conditions is used to derive a spatial spectroscopy of the defect distribution in hydrogenated amorphous silicon. The results show conclusive evidence for a defect density profile extending from the a-Si:H/air interface toward the bulk in samples deposited by rf glow discharge under standard conditions at low substrate temperature (373 K). This spatial inhomogeneity in defect density almost completely disappears after annealing at 473 K and also seems absent if the material is deposited at higher temperature (523 K). These results are supported by a model in which the surface defects, buried during a-Si:H deposition, are annealed out in a thermally activated process.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 58 (1985), S. 1292-1301 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The admittance of Schottky diodes formed on dc triode sputtered amorphous hydrogenated silicon has been measured as a function of frequency at zero dc bias. The electrical behavior of the device is modeled with an equivalent circuit taking into account the thermal response time of gap states and the transport of carriers in the conduction band. The theoretical frequency dependence of the admittance of the Schottky diode is derived in two limiting cases: whether the occupancy of the gap states is controlled mainly by their interaction kinetics with the extended states or by the transport of electrons in the conduction band. We reach the conclusion that, in our samples, the response to an ac modulation is limited by the interaction kinetics of the localized states with the extended states of the conduction band. We apply this analysis to samples exposed to different sputtering conditions. The results show that, with these samples, not only the density of deep gap states at the Fermi level but also their efficiency for the capture of electrons decreases with hydrogen incorporation. These variations correlate well with the evolution of the electron mobility-lifetime product obtained from independent photoconductivity measurements.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 3351-3353 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The density of states at the Fermi level N(EF) has been measured on hydrogenated polymorphous (pm-Si:H) silicon samples using both capacitance measurements on Schottky barriers and space-charge-limited current measurements on n+/i/n+ structures. From both techniques, N(EF) values of 7–8×1014 cm−3 eV−1 have been obtained, which is significantly lower than reported in the literature for hydrogenated amorphous silicon (a-Si:H). Such values demonstrate that pm-Si:H is a very low defect density material which should be able to replace a-Si:H in the field of applications like photovoltaics. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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