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  • 1
    ISSN: 1432-1009
    Keywords: KEY WORDS: Functional unit; Life cycle assessment; Life cycle inventory analysis; Degreasing processes; Metal processing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: 1 and C2 hydrocarbons (trichloroethane, trichloroethene, tetrachloroethene, dichloromethane). Measures aiming at the reduction of toxic emissions and ozone depletion potential (ODP) may possibly lead to a shift of environmental impacts towards higher energy consumption, emission of waste water, and volatile organic compounds (VOC) with photochemical oxidant creation potential (POCP). The present article concerns itself with a life cycle assessment of the three main degreasing processes in order to compare their integral environmental impacts with one another. This is supplemented by presenting the methodology of the life cycle inventory life cycle inventory analysis (LCI). Generally, the applicability of the established LCI method can be shown quite clearly. However, some difficulties arise, especially at the stage of the goal definition, as the use of the process and the functional unit cannot be pinned down as easily and neatly as for most other products. The definition of the use of the process and the functional unit is not as straightforward as for most products. Among the potential functional units identified are the mass of removed impurities, cleaning time, cleaning work, percentage of purity, throughput of parts, loads, mass or surface and virtual coefficients. The mass of removed impurities turned out to be the most suitable parameter for measuring the technical performance of degreasing processes. The article discusses background, purpose, scope, system boundaries, target group, process tree and representativeness of the present study.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-4475
    Keywords: Gas chromatography ; Polyphenyl ethers ; Lubricants, synthetic
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The described synthesis of synthetic lubricants based on polyphenyl ethers requires an analytical characterization of the isomerization step, which is important to the process optimization. The separation of the intermediates succeeds with gas chromatography; the isomers are determined using a retention index system. The obtained results are compared with the composition of the final product, which was investigated by HPLC analysis.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1572-9729
    Keywords: defluorination ; difluorocatechols ; difluorophenols ; metabolism ; Penicillium ; phenol hydroxylase
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The Penicillium frequentans strain Bi 7/2, using phenol as a sole source of carbon and energy,transformed the fluorinated phenols 2,3-, 2,4-, 2,5-and 3,4-difluorophenol rapidly. After growth on phenol, resting mycelia of the fungus converted the difluorophenols completely at an initial concentration of 0.5 mM within 6 hours. The corresponding difluorinated catechols were found to be intermediates of all difluorophenols investigated. A relatively unspecific phenol hydroxylase catalyzed this hydroxylation step and showed activities towards all difluorophenols tested. One difluorocatechol was formed from each difluorophenol substituted with fluorine in the ortho-position, whereas two catechols were formed from 3,4-difluorophenol, due to its two vacant ortho-positions. A partial defluorination (50-77%) was observed in all cases.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 68 (1996), S. 573-575 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 71 (1999), S. 111-117 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 559 (1988), S. 118-122 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Arylvanadium Compounds. XIII. Synthesis and Properties of Mesityl Vanadium(V) CompoundsVOCl3 reacts with dimesityl zinc forming MesVOCl2. This compound is very reactive and decomposes above room temperature with elimination of mesityl chloride. VOMes3 is obtained from LiVOMes3 by oxidation. Its thermal and reactive behaviour is viewed. VOMes3 forms with VMes3 the compound (VMes3)2O.
    Notes: Durch Umsetzung von VOCl3 mit ZnMes2 wird MesVOCl2 erhalten. Es ist eine sehr reaktive und thermisch labile Substanz, die Mesitylchlorid eliminiert. Es gelang nicht, durch weitere Substitution Mes2VOCl oder VOMes3 herzustellen. VOMes3 ist durch Oxydation von LiVOMes3 zugänglich. Sein thermisches und reaktives Verhalten wird beschrieben. Durch Umsetzung von VOMes3 mit VMes3 bildet sich (VMes3)2O.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 577 (1989), S. 229-233 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of 1,3-Diketonato Vanadium(III) HalidesVanadium(III) acetylacetonate reacts with the halides VX3(thf)3 (X = Cl, Br) in tetrahydrofuran by ligand exchange forming the mixed complexes V(acac)3-nXn(thf)min good yields. The procedure is applicable to other diketonato vanadium(III) compounds.
    Notes: Die Acetylacetonatovanadium(III)-halogenide V(acac)3-nXn(thf)m (X = Cl, Br) lassen sich aus Vanadiumtrisacetylacetonat und den Vanadium(III)-halogeniden durch Ligandenaustausch in Tetrahydrofuran in guten Ausbeuten gewinnen. Die Methode ist auf andere 1,3-Diketonatovanadium(III)-Verbindungen übertragbar, wie anhand der Benzoylacetonat-Komplexe gezeigt wird.
    Type of Medium: Electronic Resource
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