ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
13C Chemical shifts are reported for the ruthenium(II) tris complexes of thirteen 2,2′-bipyridyls and three 1,10-phenanthrolines and for the osmium(II) tris complexes of five 2,2′-bipyridyls. Chelation induced shifts (δcomplex - δligand) are discussed in terms of models for π back-bonding. 13C NMR is shown to be a convenient tool for the direct observation of the geometrical isomerism of complexes formed from monosubstituted ligands.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270220609
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