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  • 1
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The trivanadium-substituted heteropolytungstates M5H3GaW9V3O40·xH2O (M = Me4N, Et4N or K) have been prepared from their lacunary precursor, α-Na9GaW9O34H2, and characterized by elemental analysis, 51V- and 183W-n.m.r. spectroscopy, and electrochemistry. The 183W-n.m.r. spectrum of the title anion consists of two lines as expected for the C 3v structure of the trisubstituted A-α-Keggin anion.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 20 (1995), S. 1215-1236 
    ISSN: 0271-2091
    Keywords: square obstruction ; channel flow ; vortex shedding ; sliding walls ; numerical calculation ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results are presented for the unsteady, two-dimensional flow and heat transfer due to a square obstruction of diameter d located asymmetrically between the parallel sliding walls of a channel with length-to-height ratio W/H = 6·44. Analysis is based on the numerical solution of spatially and temporally second-order accurate finite difference approximations of the transport equations expressed in curvilinear co-ordinates. Laminar, constant property flow is assumed for obstruction configurations in which the blockage ratio is d/H = 0·192, the nearest-wall distances are g/d = 0·2, 0·5 and 1, the orientation angles are α=0°, 10° and 20° and the Reynolds numbers are Re=100, 500, and 1000. Preparatory testing of the numerical procedure was performed for a variety of documented flows to verify its physiconumerical accuracy and obtain estimates of the residual grid-dependent uncertainties in the variables calculated. Heat transfer, drag and lift coefficients and Strouhal numbers for the present flow were finally calculated to within 4%-7% of their grid-dependent values using non-uniformly spaced grids consisting of (x=99, y=55) nodes. Above a critical value of the Reynolds number, which depends on the geometrical parameters, the flow is characterized by alternate vortex shedding from the obstruction top and bottom surfaces. Streamline, vorticity and particle streakline plots provide qualitative impressions of the unsteady vortical flow. Especially noteworthy are the extremes in the lift coefficient which ranges from large positive values for an obstruction with g/d=0·2 and α=10° to negative values for one with g/d=0·5 and α=0°. Both the drag and lift coefficients as well as the Strouhal number exhibit non-monotonic variations with respect to the parameters explored. Asymmetries in the obstruction location and orientation account for relatively large vortex-induced periodic variations in heat transfer, especially along the wall nearest the obstruction. Notable differences are also predicted for the heat transfer coefficients of the individual obstruction surfaces as a function of the orientation angle.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ [u.a.] : Wiley-Blackwell
    Journal of Orthopaedic Research 7 (1989), S. 61-67 
    ISSN: 0736-0266
    Keywords: Blood flow ; Diaphyseal bone ; Microspheres ; Endosteal cortex ; Periosteal cortex ; Life and Medical Sciences
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: Blood flow rate in the periosteal and endosteal cortices of the diaphysis of long bones was determined in eight anesthetized adult dogs using the radioactively labeled microsphere method. The flow rate in endosteal and periosteal cortices is not significantly different unless the endosteal cortex contains cancellous bone from the medullary cavity. The highest flow rate is in the ulna, with 6.50 ml/min/100 g for the endosteal cortex and 5.15 ml/min/100 g for the periosteal cortex. The lowest flow rate is in the femur, with 2.89 ml/min/100 g for the endosteal cortex and 2.29 ml/min/100 g for the periosteal cortex. The results of this study indicate that variation of blood flow does exist between bones of dogs. However, the flow rates of individual bone on the left and right sides in the same dog are not significantly different. This indicates that the data are reproducible and reliable, and differences are not an inaccuracy of the radioactively labeled microsphere method. The results also demonstrate that there are no significant differences in bone blood flow as measured with small numbers (fewer than 400 microspheres per sample) and large numbers (more than 400 microspheres per sample) of microspheres. The adequate number of microspheres in each bone sample is 150-250. Therefore, a dose of 0.5 × 106 spheres/kg body weight can be sufficient.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 29 (1997), S. 393-414 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Principal component analysis, an advanced technique of sensitivity analysis, has been used to determine reduced mechanisms that can model species and temperature profiles in Plug Flow Reactors (PFR), Premixed Laminar Flames (PLF), and Perfectly Stirred Reactors (PSR) for two H2/air and two CH4/air mechanisms over a range of input parameters including initial temperature, equivalence ratio, and residence time. The results show that principal component analysis can be used effectively to reduce a comprehensive mechanism that contains unimportant reactions to a reduced mechanism that contains necessary and sufficient reactions. The accuracy of a reduced mechanism determined from principal component analysis can be easily controlled by carefully selecting reduction criteria. For the conditions chosen here, namely the requirement that radical profiles computed with reduced and comprehensive mechanisms agree to within 5%, substantial reductions were not achieved. Principal component analysis is able to resolve the influence of stoichiometry, combustor type, and mechanism on mechanism reduction.The two H2/air mechanisms were each reduced to mechanisms that can model all the cases considered, and the extent of reduction in each was very similar and modest. For H2/air chemistry, equivalence ratio had little effect on reduction. Combustor type was slightly more influential with the number of required reactions decreasing from PFR to PLF to PSR combustion. Relative to the H2/air system, principal component analysis of the CH4/air system is more difficult because of mechanism size. For CH4/air combustion, if we consider all equivalence ratios, PLFs require the most reactions, if individual equivalence ratios are examined, PFRs require the greatest number of reactions. Combustor type influences mechanism reduction substantially because of the different couplings between the fluid mechanics and chemistry. In H2/air combustion rich combustion required the fewest reactions and in CH4/air, it required the most. Reduction must be achieved by considering the entire mechanism since reactions interact in concert, for example, reactions unimportant in one CH4 mechanism are often important in the other. © 1997 John Wiley & Sons, Inc. Int J Chem Kinet 29: 393-414, 1997.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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