ISSN:
1432-1130
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A chemically modified carbon paste electrode was prepared by incorporating appropriate amounts of sodium humate(NaA). Palladium(II) was selectively accumulated in a solution of Britton-Robinson(B-R) buffer (pH 2.8) onto the electrode surface in open circuit mode. The subsequent electrochemical measurement was carried out by cyclic voltammetry (CV) and linear sweep anodic stripping voltammetry (LSASV) in a supporting electrolyte of 1.0 M HCl. The obtained oxidation currents (Ipa1 and Lpa2) were proportional to the Pd(II) concentration in the range of 4.7 × 10–6 - 9.4 × 10–8 M. The developed method was applied to the quantitative determination of palladium in real samples.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/s002160051150
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