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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 2337-2350 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New processable polyaromatic ether-keto-sulfones were prepared from 2,2′-diiododiphenyl-4,4′-dicarbonyl dichloride (I), bis(p-phenoxybenzene)sulfone (II), isophthaloyl chloride (III), and diphenyl ether (IV) in Friedel-Crafts-type polymerizations. In the most promising of the iodine-containing polymers phenylacetylenyl groups were introduced in place of iodine. This polymer, with an initial monomer ratio of I:II:III:IV = 1:5:7:3, was further investigated. It is soluble in DMF, DMA, pyridine, and sulfuric acid. After curing it was insoluble in all solvents used and lost only 1.1% of its weight at 300°C when heated in air for three days. Hence in this cured state it has excellent chemical and thermal resistance. It can be cast into a film from solution in DMAc and a glass fiber laminate is readily prepared. The film is tough, transparent, and brown in color. The cured film is tougher than the uncured. The glass fiber laminate is also tough and fairly flexible. A distinct advantage of this type of polymer is its ready availability in relatively cheap raw materials. The phenylacetylenyl-group-containing polymer showed a transition temperature at 175°C and two exotherm peaks at 243 and 361°C which disappeared after curing in a DSC thermogram. Before and after curing this polymer displayed softening temperatures at 149 and 171°C, respectively, measured by a Vicat apparatus at a heating rate of 1°C/min. No melting temperatures up to 500°C were observed for any of the polymers in this study.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 495-503 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New Processable Polyaromatic amides were prepared from 2,2′-diiododiphenyl-4,4′-dicarbonyl dichloride (I) and several aromatic diamines. Phenylethynyl groups were introduced in these polymides by replacing the iodine groups with copper phenyl acetylide. On thermal curing, 2,2′-di(phenylethynyl)biphenyl group undergoes intramolecular cyclization to form 9-phenyl dibenzanthracene derivative. The cured polymers showed increased heat and chemical stabilities. No melting points were observed for all the polymers below 500°C. The viscosity of the polymers was decreased on substitution of the iodine by phenylethynyl groups.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 8 (1986), S. 164-167 
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Traditionally, an instrument such as an Instron rheometer or thermal analysis is used to characterize the processing conditions of a plastisol. The Instron rheometer is useful only when the material begins to build up mechanical strength. A rheometer such as a Plasti-corder suffers from the requirement of large sample and low sensitivity toward rheology change caused by phase variation. Thermal analysis only responds to the heat capacity and enthalpy changes at transitions occurring during plasticization. The plasticization involves only weak thermal change and is difficult to detect by thermal analysis. However, the more sensitive method of dielectrometric analysis, which needs only a small sample, was used to detect any rheological change of a plastisol during plasticization. Because the information obtained is from molecular motion, the results are accurate and the speed of characterization is rapid.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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