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Direct analysis of C60 and related compounds with electrospray mass spectrometry (1995)

Liu, Tsang-Yu ; Shiu, Lung-Lin ; Luh, Tien-Yau ; [et al.]

New York, NY : Wiley-Blackwell

Rapid Communications in Mass Spectrometry 9 (1995), S. 93-96

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Details

ISSN: 0951-4198

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Physics

Notes: Without performing any charge transfer chemical reaction, C60 and its derivatives could be analyzed directly by electrospray mass spectrometry. Oxidation or reduction at the metal/solution interface of the probe tip was probably responsible for the formation of these radical cations and anions. This technique appeared to be superior to desorption chemical ionization and fast-atom bombardment ionization in the analysis of C60 derivatives because the mass spectra were characterized by molecular ions with little or no fragmentation.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/rcm.1290090120

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