ISSN:
0935-9648
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The necessity for a rational interpretation of scanning tunneling microscopy (STM) and atomic force microscopy (AFM) images is demonstrated by our recent STM/AFM studies of layered transition-metal chalcogenides, layered transition-metal halides, organic conducting salts, and alkanes adsorbed on graphite. To a first approximation, the STM image of a surface is described by the partial density plot ρ(r0, ef) of the surface, and the AFM image by the total density plot ρ(r0). The contribution of an atom to the ρ(r0, ef) plot increases with decreasing distance to the tip and with increasing electronic contribution to the energy levels around the Fermi level. Since the atoms that protrude more do not necessarily make greater contributions to the energy levels near the Fermi level, it is difficult to achieve a rational interpretation of STM images unless appropriate partial density plots are calculated. For a variety of layered compounds, the STM and AFM images are well simulated by the ρ(r0, ef) and ρ(r0) plots calculated by the extended Hückel tight-binding electronic band structure method. Partial and total density plot calculations provide not only a basis for a rational interpretation of ideal STM and AFM images but also a step toward systematic studies of how tip-surface interactions and tunneling conditions affect the images.
Additional Material:
16 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/adma.19940060504
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