Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
88 (1988), S. 2393-2397
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Rate coefficients for the O+C2H6 reaction have been measured using the high-temperature photochemistry (HTP) technique. Strong non-Arrhenius behavior is observed. The data are well fitted by the empirical expression k(T)=1.9×10−31 T6.5 exp(−138 K/T) cm3 molecule−1 s−1. Confidence limits are discussed in the text. The results are consistent with calculations based on transition state theory and tunneling through an Eckart barrier.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.454022
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