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  • 1
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 113-117 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Random multiblock copolymers of bisphenol-A-polycarbonate and poly(dimethylsiloxane) were hot-pressed or solvent cast into films which were studied by dynamic mechanical methods over the range 11 to 110 hertz (Hz) and 100 to more than 2200 Hz, respectively. The samples were studied also by differential-scanning calorimetry. The two phases are separated well in spite of the low-molecular weights of the blocks. This separation is altered by thermal history and by the solvent medium when solvent casting is used to prepare the films. The damping properties do not vary greatly with frequency. Damping is greatest near the glass-transition temperatures of the two components. The expansion of the block copolymer with heat appears to be retarded by the polycarbonate phase until the glass transition of that phase is approached.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 439-445 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Representative random, alternating block copolymers of polydimethylsiloxane (PDMS) and bisphenol-A-polycarbonate (BPAPC) were studied by thermomechanical and dynamic mechanical techniques. Data on glass transition temperatures (Tg), heat-deflection temperatures (Td), Vicat softening temperatures (Ts), coefficients of linear expansion (α), stress-strain, and stress relaxation for four PDMS-BPAPC block co-polymers are presented. The effect of casting films from mixed n-hexane-methylene chloride solution on the thermomechanical and dynamic mechanical properties was also studied.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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