ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The title compound was synthesized by the reaction of [H3O+·18-crown-6][Cl-H-Cl−]·3.8 C6H5Me with two equivalents of H2O. Colorless crystals, which slowly deposited from the corresponding liquid clathrate, belong to the monoclinic space group P21/n witha=10.648(6),b=9.571(2),c=20.801(6) Å,β=98.67(5)°, andD c=1.24 g cm−3 forZ=4. Refinement based on 1609 observed reflections led to a finalR value of 0.072. In the crystal structure the [H3O+·18-crown-6]+ cations are packed in layers separated by puckered sheets of [(H5O 2 + )(Cl−)2]−.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01160659
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