ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The CO adsorbed on CoO-MgO solid solutions with high specific surface areas is bound to three different types of surface centers. The first type is a pair of Co2+ ions, one in octahedral coordination and one in square pyramidal coordination, each weakly interacting with neighboring ions. The second type of center is an individual Co2+ ion in square pyramidal coordination and strongly interacting with neighboring Co2+ ions in the same coordination. The third type of center is a variant of the second, one ion Co2+ ion in square pyramidal coordination interacting with neighboring Co2+ ions in octahedral coordination. 2. The CO molecule bonds more firmly to centers of the first type than to centers of either of the other types.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00924547
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