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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular medicine 29 (1951), S. 553-554 
    ISSN: 1432-1440
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 4966-4979 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Using a point-dipole model, we discuss short- and long-range interactions in a 2D array representing a monolayer. Long-range forces may be treated exactly if the film is homogeneous at the wavelength scale and if the effective polarizability including short-range forces is known. Reflection and transmission amplitudes for polarized light are calculated for two monolayer models taking the subphase into account for arbitrary incidence angle and reflection strength. Experimental results are then compared to the theory. The good agreement shows that oblique incidence reflection and transmission spectra are valuable tools for investigating orientation and organization of chromophores in monolayers. Although in most of the studied cases—including J aggregates—the dye chromophore lies flat on the water surface, two instances are presented of molecular aggregates whose transition moments are vertical.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 49 (1982), S. 545-558 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Measurements of the thermal conductivity are reported for an 80%3He-20%4He mixture above the critical point along several isotherms and near-critical isochores, using the same techniques and apparatus described for a study of3He. Using again the assumption that the observed conductivity λ can be decomposed into a sum of a regular and a singular contribution λreg and λsing, it is shown that along two near-critical isochores, λsing diverges. In particular, along the isochore showing the largest λ at the phase transition, the divergence is nearly the same as for3He and can be roughly characterized by a simple power law (T-Tc)−ψ with Ψ≈0.58. This observation is contrary to predictions that foresee λsing→0 asT c is approached. The relaxation times characterizing the attainment of steady state conditions after switching the heat flux on and off show a similar behaviour as a function of reduced temperature as do those for pure3He. This result might indicate a substantial coupling between concentration and entropy diffusion. In the Appendix, the correlation length for3He nearT c is calculated from heat conductivity, viscosity, and specific heat data.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 57 (1984), S. 31-54 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We report an analysis of NMR lineshape measurements in hcp single crystals of H2 at ortho concentrationsX between 0.15 and 0.55 over the temperature range where the orientational ordering becomes substantial. The normalized rms order parameter $$\bar \sigma $$ is obtained from the second momentM 2 and is plotted against the reduced orientational entropyS red derived from calorimetric measurements. For comparison, we present calculations for a single-particle model, for isolated pairs and triangles ofo-H2 molecules. They confirm that single-particle models as used by previous authors cannot satisfactorily account for the orientational ordering in the hcp phase. Rather, cluster configurations where the lowest excited states have a quite different ordering arrangement from that of the ground state, yet only a small energy change, need to be invoked. In a $$\bar \sigma $$ versus 1−S red plot, the hcp phase ordering is contrasted with that in the ordered cubic phase. In the Appendix, the experimental sample cell design at Duke University and the observed NMR line shapes are compared with those of the groups at Saclay and Harvard University under similar conditions ofT andX and the differences in results are discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 57 (1984), S. 265-282 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We report thermal conductivity measurements of two hcp H2 crystals over a temperature range between 0.15 and 1.6 K and an ortho-H2 concentration range betweenX=0.55 andX=0.01. The orientation of the crystals in the conductivity cell was determined from the anisotropy of the NMR spectrum forX≈0.01. The conductivity results are analyzed into contributions from (1) phonon scattering by the rotational states of the ortho-H2 particles and (2) boundary phonon scattering. The results are compared with previous work at higher temperatures. The influence of ortho-H2 clustering on the thermal conductivity is observed and discussed.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Naturwissenschaften 48 (1961), S. 377-378 
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 107 (1997), S. 175-196 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We report new measurements of the effective thermal conductivity Keff and relaxation time τ in dilute mixtures of3He in superfluid4He, with molar concentrationsX≤10−3. The temperature range extended fromT≈1.4 K toT λ. Both Kcff and τ are found to agree with theoretical predictions, in contrast to previous experiments where significant differences were observed. A new thermal conductivity cell design was used which almost completely eliminates extraneous volumes and surfaces, and the earlier results are explained in relation to these design changes.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 109 (1997), S. 801-810 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have measured the thermal response of a superfluid 4 He layer near Tλ to a time-varying heat flux. In the low-frequency range studied, 1 × 10 −3 〈 f 〈 0.1 Hz, we find the response to be independent of the applied frequency f, a result consistent with the expectation that the measured response is due to the boundary resistance Rb alone. These findings differ from those by Olafsen and Behringer. The thermal conductivity cell used by these authors had extraneous surfaces in contact with the superfluid which were eliminated in the cell used for our experiments; we believe these surfaces were responsible for the frequency dependence observed in previous work. Furthermore, we show that AC and DC measurements of Rb differ by no more than 1%, and that both exhibit a weak singularity near Tλ.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 109 (1997), S. 801-810 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have measured the thermal response of a superfluid4He layer nearT λ to a time-varying heat flux. In the low-frequency range studied, 1×10−3〈f〈0.1 Hz, we find the response to be independent of the applied frequencyf, a result consistent with the expectation that the measured response is due to the boundary resistanceR b alone. These findings differ from those by Olafsen and Beharinger. The thermal conductivity cell used by these authors had extraneous surfaces in contact with the superfluid which were eliminated in the cell used for our experiments; we believe these surfaces were responsible for the frequency dependence observed in previous work. Furthermore, we show that AC and DC measurements ofR b differ by no more than 1%, and that both exhibit a weak singularity nearT λ.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 108 (1997), S. 161-189 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The local density response is studied in a simple fluid near the liquid-vapor critical point, subjected to temperature oscillations of its container. This investigation provides a new approach in the study of the adiabatic energy transfer (“piston effect”) in the fluid. The density response functionZ F (ω, ε,z) is calculated for3He in the absence of stratification, where ω is the angular frequency, ε=(T−T c )/T c the reduced temperature,T c =3.316 K the critical temperature, andz the vertical position in the container. Experiments are described where the density is measured by two superposed capacitive sensors in a cell of 3.5 mm height, and where the temperature oscillation frequencyf=ω/2π is varied between 10−4 and 2 Hz. Over the experimental range 5×10−4〈ε〈5×10−2 there is in general reasonable agreement between predictions and experiments. The systematic departures might be accounted for by deviations from 1D geometry, which were not included in the calculations. Over the frequency and reduced temperature ranges, the damping effect from the critical bulk viscosity is predicted to be too small to be detectable. The observed effect of the stratification and its frequency dependence inZ F are briefly discussed. In the appendix, the predicted critical acoustic attenuation from the bulk viscosity is compared with published data, the effect from finite thermal conductivity of the fluid container plates and also the corrections toZ F for the effects of the cell sidewalls are calculated.
    Type of Medium: Electronic Resource
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