ISSN:
1573-1111
Keywords:
Inclusion compound
;
hydroxy compound
;
crystal structure
;
thermal analysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The crystal and molecular structures of the title host compound (I), C35H26O, and its inclusion complexes with water (II), C35H26O·H2O and dimethylsulphoxide (III), C35H26O·C2H6OS are reported. (I) is monoclinicC2/c,a = 9.725(1),b = 20.031(3),c = 26.545(3) Å, β = 90.60(1)0,V = 5170 Å3,Z = 8; (II) is triclinic, $$P\bar 1$$ ,a = 10.206(1),b = 10.324(2),c = 14.425(2) Å, α = 101.68(1), β = 89.92(2), γ = 116.34(1)0,V = 1327 Å3,Z = 2; (III) is monoclinicP21/n,a = 17.832(5),b = 10.109(3),c = 17.901(5) Å, β = 111.93(2)0,V = 2993 Å3,Z =4. The structures were solved by direct methods and refined to final residuals of 0.045, 0.048, and 0.071, respectively. Thermal analysis of the complexes corroborates the crystallographic results.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01133229
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