ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The title compound is orthorhombic,M r =590.2,P212121 (No. 19),a=9.865(2),b=9.924(2),c=31.202(7) Å,V=3055(2) Å3,Z=4,D x =1.283 g cm−3, λ(MoK α);F(000)=1256; μ(MoK α)=6.76 cm−1, finalR=0.052 for 1441 reflections ∥I≥2.5σ(I)∥. The nitrite group is chelated via the two oxygen atoms; the two six-membered rings resulting from the coordination of the 1,3-propanediamine ligands to the nickel(II) atom are in the chair conformation. The Ni-N and Ni-O distances average 2.07(1) and 2.14(2) Å respectively. The two Ni-O distances are nearly equivalent.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01161429
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