ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Poly[thio(thiocarbonyl)oxy-1,4-cyclohexyleneoxy(thiocarbonyl)thiomethylene-1,4-phenylenemethylene] (4) was obtained from 4-bromomethylbenzyl bromide (1), dipotassium 1,4-cyclohexanediolate (2) and carbon disulfide at low temperature by using 1,4,7,10,13,16-hexaoxacyclooctadecane as catalyst. At high temperatures, poly[oxy-1,4- cyclohexyleneoxymethylene-1,4-phenylenemethylene] (8) was obtained from the reaction between 1 and 2, however. Mechanisms are proposed for these reactions.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1980.021810501
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