ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract Crystal structure of the title compound belonging to the group ofα-acylimino derivatives of sulfur(II) compounds has been determined by X-ray structure analysis. The crystals are monoclinic, P21/c,a=11.210(2),b=8.197(1),c=13.659(2) Å,β=102.36(2)°,V=1226.0(3) Å3,Z=4,D x =1.61 g cm−3, λ(MoKα)=0.71069 Å,μ=6.3 cm−1. The structure has been refined to a finalR value of 0.035 for 1401 observed reflexions. The molecule is nearly planar with symmetrym. The title compound contains a very short intramolecular C=O⋯S contact of 2.328(3) Å, suggesting a ‘bond-non-bond’ resonance interaction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01185387
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