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  • 1
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 543-545 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The title compound, bis{1-[(+)-(1R,3S)-1,2,2,3-tetramethylcyclopentyl]-3-[(-)-(1S,3R)- 1,2,2,3-tetramethylcyclopentyl]propane-1,3-dionato-O,O'}nickel(II), [Ni(C21H35O2)2], displays interesting stereochemical aspects due to the meso configuration of the 1,3-bis(1,2,2,3-tetramethylcyclopentyl)-1,3-propanedionate ligands. The Ni atom lies on an inversion center, with Ni—O distances of 1.842 (2) and 1.826 (2) Å.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 89-93 
    ISSN: 0935-6304
    Keywords: Gas chromatography, GC ; Capillary columns ; glass ; Complexation GC ; Chiral complexation GC ; Enantiomer separation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The enantiomer separation of 2-halocarboxylic acid esters on two chiral nickel(II) bis-((perfluoroacyl)terpeneketonates) by complexation gas chromatography is described. The quantitative entiomer separation of branched 2-halocarboxylic acid esters is achieved with nickel (II) bis (3-(heptafluorobutanoyl)(1R, 2S)-pinan-4-onate) 1 while unbranched 2-halocarboxylic acid esters are preferably separated on nickel(II) bis(3-(heptafluorobutanoyl)-(1S)-10-methylenecamphorate) 2. The metal chelates 1 and 2 are accessible in both enantiomeric forms allowing the determination of the enantiomeric excess (ee) effective and reliable.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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