ISSN:
1572-8862
Keywords:
Oxide-bound η3-allylrhodium
;
model cluster
;
organometallic oxide cluster
;
V4O4 ring
;
η3-allyl cluster
;
diene cluster
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract Reaction of [(η3-C4H7)2Rh(CH3CN)2]PF6(η3-C4H7 = β-methallyl) with [n-Bu4N](VO3) gives a new η3-allyl cluster [n-Bu4N]2[{(η3-C4H7)2Rh}2 (V4O12)] (I) which is readily converted into a diene cluster, [n-Bu4N]2 [{(η4-C8H14)Rh}2(V4O12)] (II) (C8H14=2,5-dimethyl-1,5-hexadiene) by reacting with CO or P(OEt)3;I andII have been characterized crystallographically.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00702958
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