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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This work investigated the changes in the permeability of high-alumina self-flowing refractory castables based on calcium aluminate cement (CAC) and hydratable alumina binder (HAB) pretreated between 110° and 1650°C. Permeability constants k1 and k2 were fitted from Forchheimer's equation based on airflow tests conducted at room temperature. The results indicated that dehydration was the main contributing factor for increased permeability in bodies pretreated up to 600°C and that sintering effects prevailed between 900° and 1650°C. Castables based on HAB were less permeable than those based on CAC, a behavior ascribed to the type of hydrates formed and to the particle-packing features of the matrix and the matrix–aggregate interfaces.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 86 (2003), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The purpose of this work was to investigate the drying kinetics of high-alumina, ultra-low-cement refractory castables under continuous heating conditions. Three main drying stages were identified during the castable heat-up and were related to the phase change of free water and to the decomposition of hydrated products present in the body. A clear correlation was found between the actual heating profile inside the castable and the dewatering stages under various heating schedules. Thermal analysis was used to assess the drying temperature that represents the highest risk of steam pressure buildup and, thus, of explosive spalling.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper reports on the use of Jack bean meal as an alternative source of urease for direct coagulation casting (DCC) processes. Al2O3 suspensions were prepared to compare the effect of Jack bean meal and pure urease on the hydrolysis of urea, the slurry coagulation rate, and the mechanical properties of consolidated bodies. Results indicate that the Jack bean meal is a promising economic alternative for the consolidation of ceramic parts, mainly because of its lower susceptibility to enzyme deactivation when exposed to room temperature and relatively humid environments.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This work describes the use of a new permeametry technique to evaluate microstructural changes that take place in castables with high alumina-fiber content during the dewatering process. It is shown that the mass loss due to cement dehydration and the permeability increase caused by fiber burnout can be independently assessed, based on the fluid dynamic conditions established for the experiment. Control of the pressure drop through the sample was the key procedure used to analyze the phenomenon of interest.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Coagulation methods originally developed for colloidal processing were investigated in this paper as alternative approaches to consolidate high-alumina refractory castables free of hydraulic binders (zero-cement). Three in situ reactions based on the direct coagulation casting (DCC) technique were evaluated to promote castable coagulation: (1) the autocatalytic hydrolysis of gluconic acid lactone, (2) the gradual dissolution of hydroxyaluminum diacetate particles in water, and (3) the enzyme-catalyzed hydrolysis of urea. The coagulating behavior of castables and matrix-representative suspensions was investigated with the help of zeta potential analysis, pH measurements, castable free-flow evaluation, and oscillatory rheological tests. The enzyme-catalyzed hydrolysis of urea seemed to be the most appropriate mechanism to promote the coagulation of initially self-flow zero-cement refractory compositions.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper proposes a novel direct casting method of alumina suspensions using alginic acid salt and the coagulation agent hydroxyaluminum diacetate (HADA). These two compounds allowed the consolidation of alumina suspensions through a simultaneous time-delayed physical and chemical gelation process. The physical gel was formed by the gradual release of aluminum and acetate ions from the HADA in water, while the chemical gel originated from the cross-linking of alginate molecules by the polyvalent aluminum ions. Wet alumina green bodies displayed enhanced mechanical properties with the addition of minimal contents of organic material (〈0.1 wt%).
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this work, the water-expulsion porosimetry technique was used to quantify the permeable pores of self-flow ultralow-cement refractory castables that were treated at 600°–1650°C. Results have shown that the method as proposed in previous works was not valid, because water was not removed continuously from pores, relative to increased pressure. Nevertheless, the maximum pore diameter obtained according to ASTM Method E128-89 could be successfully correlated with other castable physical properties (such as the permeability constants from the Forchheimer equation) and the apparent porosity obtained via the Archimedes technique. Although the apparent porosity decreased as the thermal treatment temperature increased, the pore morphology changed continuously, with the generation of less-tortuous and more-permeable paths for fluid flow.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Considerable efforts have been made to understand the dewatering behavior of refractory castables. Modeling of this process must be based on realistic heat and mass transfer data; hence, consistent values of castable properties are required, particularly permeability values, since these are the most important parameters that govern the process. Permeability values, however, are usually obtained at room temperature and therefore may not reflect the remarkable microstructural changes that take place during water removal. The problem has become more critical for castable compositions based on calcium-free binders, in which the dehydration process is still unclear and explosive spalling is more likely to occur. This study has investigated the behavior of the dynamic permeability of high-alumina calcium-free refractory castables subjected to a drying process up to 700°C. Samples were previously treated at temperatures ranging from 110° to 1650°C to provide information on the castables’ reversible and irreversible microstructural changes. The results revealed fluctuations and a dramatic decrease in the permeability level near 200°C, which may help to explain the occurrence of explosive spalling in this class of castables.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Temperature is an important factor affectng the permeation of fluids in refractory castables. Because of experimental difficulties, however, permeability parameters are usually obtained at room temperature and then extrapolated to the temperature of interest, with no concern regarding porous structure modification (thermal expansion, etc.). In this work, an apparatus has been developed to evaluate the air-flow permeability of refractory castables at temperatures up to 800°C. The objective is to investigate modifications in the permeability constants obtained by Forchheimer's equation to provide a more realistic relationship with castable processing and molten-metal corrosion parameters.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Correct estimation of the pressure drop in filtration processes that involve fluid velocity variations is of major importance, because it allows the filtration rate and/or the energy consumed on fluid flow to be more accurately controlled. Permeability of porous filters has been often described by Forchheimer's equation, which establishes a nonlinear dependence between pressure drop and fluid velocity. Two constants, k1 and k2, dependent only on the medium, quantify the viscous and inertial effects on the pressure drop curve. In this work, experimental data of airflow through 10 pores per linear inch ceramic foam filters are used to show that a single sample may have completely distinct permeability constants depending on the data range chosen for analysis. The Darcian permeability constant k1 displays higher variation than the non-Darcian permeability constant k2. The conclusion is that special attention must be taken to represent permeability of highly porous structures in a large velocity range. The predictability of Forchheimer's equation generally worsens when less data are included in the curve fitting, particularly at low velocities. Careful consideration should be made if constants k1 and k2 are intended to be used for permeability estimation beyond the fitting range.
    Type of Medium: Electronic Resource
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