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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 1974-1982 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Improvement in thermally stable, low-resistance ohmic contacts to n-type GaAs is reported for GeInW and NiInW contact metals. Coevaporation of In with Ge or In with Ni reduced the contact resistances by a factor of about 2 compared with those of the layered structures. The reduction is believed to be due to a uniform In distribution in the contact metals in the as-deposited state which resulted in an increased area of InxGa1−xAs phases in direct contact with the GaAs substrate. Annealing the coevaporated GeInW contacts for a short time at temperatures between 900 and 980 °C resulted in a mean contact resistance of 0.5 Ω mm. Similar annealing of the coevaporated NiInW contacts at temperatures between 800 and 1000 °C resulted in a contact resistance of 0.3 Ω mm. Additionally, the thermal stability of these ohmic contacts at 400 °C after contact formation, which is required by subsequent integrated circuit process steps, was studied. Although a slight increase in the contact resistances was observed after annealing for 100 h at 400 °C for the GeInW contacts, no change in the contact resistances was observed for the NiInW contacts after annealing for 100 h at 400 °C and for 10 h at 500 °C. This excellent thermal stability of the NiInW contacts is believed to be due to the formation of Ni3In intermetallic compounds which have high melting points. The present study suggests that in order to prepare thermally stable, low-resistance contacts it is desirable to deposit a metal which forms high melting point intermetallic compounds with In and which promotes formation of uniform InxGa1−xAs phases at the metal/GaAs interfaces. Further reduction in the measured contact resistances was achieved by reducing the sheet resistance of the contact metals.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 3546-3551 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Thermal stability of self-aligned refractory metal-semiconductor field-effect transistors (MESFETs) with the universally used AuNiGe ohmic contact metallurgy or the recently developed NiInW ohmic contact metallurgy has been studied. In these devices WSi0.1 films with length down to 1 μm were used as the gate material, and AlCu was used as the overlayer material on the ohmic contacts, where a very thin Ti layer was deposited prior to the AlCu deposition. The performance of the as-fabricated devices with the NiInW ohmic contacts was as good as those with the AuNiGe ohmic contacts. During subsequent annealing at 400 °C, deterioration of the device performance (defined by the decrease in the FET square-law coefficient) was observed after annealing at 400 °C for 2 h in the devices with the AuNiGe ohmic contacts. However, excellent stability was observed in the devices with the NiInW ohmic contacts; no deterioration was observed at 400 °C for 180 h, 450 °C for 18 h, and 500 °C for 2 h. The device deterioration with NiInW contacts, which was observed after annealing for longer times, is believed to be due to an increase in the contact resistances caused by In movement away from the metal/GaAs interfaces. Based on this assumption, an activation energy for In diffusion in GaAs was determined from onset times of the device deterioration to be ∼2.0 eV, which is close to the reported value of 1.9 eV.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 2113-2121 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: To investigate the effects of microstructure of the Schottky characteristics of WSix contacts to n-type GaAs, cross-sectional transmission electron microscopy, x-ray diffraction, and secondary-ion mass spectrometry have been used to study the interfacial and bulk film microstructures. The barrier heights and ideality factors of WSi0.1 and WSi0.6 contacts were obtained by forward current-voltage and capacitance-voltage measurements. These Schottky characteristics were found to be unrelated to the bulk film microstructure, but closely related to the interfacial microstructure at the WSix/GaAs interfaces. Both the WSi0.1/GaAs and WSi0.6/GaAs interface morphologies were observed to be stable and remain smooth during annealing at 800 °C for 10 min, while a rough interface with W protrusions and Ga and As out-diffusion was observed in two-layer W/WSi0.6 contacts. The stability of the WSix interfacial microstructure is suggested to depend on both the chemical stability of the WSix films with GaAs and the intervening oxides between WSix and GaAs. Nontrivial amounts of W and Si were observed to diffuse from the WSi0.1 film into the GaAs substrate during annealing at 800 °C for 10 min. Although these in-diffused impurities in the GaAs substrate do not seem to affect the Schottky characteristics after the 800 °C annealing, they could be a potential problem in long-term stability. Of the three WSix film compositions, the single-layer WSi0.6 films were found to have the least W and Si in-diffusion and thus the best thermal stability.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 3295-3303 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: It was previously found that a small amount of In impurity was able to convert MoGeW contacts from Schottky to ohmic behavior yielding thermally stable, low-resistance ohmic contacts n-type GaAs. In the present experiment transport measurements and materials studies were carried out for MoGeInW contacts in which a thin layer of In was directly added to the MoGeW contacts during deposition. The transition from Schottky to ohmic behavior was observed by adding an In layer as thin as ∼1 nm to the MoGeW. Contact resistances were found to be very sensitive to the deposition sequence, the annealing method, the annealing temperature, and the In layer thickness. Low resistances of ∼0.5 Ω mm were obtained in the MoGeInW contacts with 2-nm-thick In layers, annealed by the heat-pulse method at temperatures in the range of 880–960 °C for 2 s. Contact resistances were stable during subsequent annealing at 400 °C for 100 h. Evidence of formation of the parallel diode areas with various barrier heights was obtained for these contacts after annealing at elevated temperatures. These low-barrier-height areas are believed to be the interfaces between the contact metals and InGaAs phases. The composition within the ternary phases was uniform, and no composition gradient was observed. The composition was determined by small-probe x-ray energy dispersive spectrum to be close to In0.2Ga0.8As. The distribution of these ternary phases, influenced by the contact fabrication process parameters, strongly affected the contact resistance.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The correlations between structural, chemical, electrical, optical properties of in situ phosphorus-doped hydrogenated microcrystalline silicon prepared by plasma-enhanced chemical vapor deposition have been studied by high-resolution transmission electron microscopy, secondary-ion mass spectrometry, electrical conductivity, and optical measurements. Microcrystallinity has been observed at a substrate temperature as low as 100 °C with a 1% dilution of (1% PH3/SiH4) in H2. In situ phosphorous-doped hydrogenated microcrystalline silicon is best grown at 200–300 °C in terms of microstructure, H and P content, and dopant activation. The effects of thermal processing and the use of silicon nitride cap deposited prior to anneal on the structure and properties of phosphorous-doped hydrogenated microcrystalline silicon are also reported. The use of a silicon nitride capping layer is shown to inhibit recrystallization of hydrogenated microcrystalline silicon during rapid thermal anneal.
    Type of Medium: Electronic Resource
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