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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 18 (1979), S. 562-564 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 24 (1985), S. 62-65 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 18 (1979), S. 316-318 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 19 (1980), S. 426-431 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 21 (1982), S. 269-271 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 18 (1979), S. 400-406 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 230-235 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reaction kinetics for the catalytic dehydrogenation of sec-butyl alcohol to methyl ethyl ketone has been investigated at atmospheric pressure and temperatures ranging from 650° to 750°F. in the presence of solid brass spheres, 1/8 in. in diameter. The nature of this catalyst permitted a direct evaluation of the surface involved in this reaction and allowed the definition of a surface-feed ratio to be expressed as S/F in place of the conventional weightfeed ratio W/F commonly used in catalytic studies. Feed compositions ranged from secbutyl alcohol to mixtures containing high percentages of methyl ethyl ketone and hydrogen.In these studies mass transfer effects were found to be significant and, for a proper representation of conditiated at the catalyst surface, must be taken into account. The effect of feed compositions on the initial rates of reaction showed that the rate-controlling step was the desorption of hydrogen involving a single-site mechanism.In addition, the results of these studies have been used to produce values of height of reactor unit HRU which have been found to correlate with mass velocity and temperature. The HRU provides a simple means of calculating the depth of catalyst necessary to effect a designated conversion.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 81-85 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Axial dispersion was studied experimentally for turbulent flow through a 1 1/4-in. piping system containing 90 deg. elbows. The Reynolds number range was 15,400 to 96,555. The imperfect pulse tracer technique was used with the axial dispersion numbers being obtained from the difference in variances of concentration-time curves observed at two points in the system.Elbows interconnected by short lengths of pipe with each succeeding one reversed so as to cause a change in the direction of flow, increased axial dispersion by 35 to 61% over that expected for straight pipe, while the same elbows turned so as to form a helix decreased the dispersion substantially; however, the amount of axial dispersion was still 8 to 22% greater than that observed for straight pipe.The equivalent lengths of the elbows depend upon both their arrangement and the Reynolds number. Closely placed, helically arranged elbows required equivalent lengths of from 2.9 to 5.1 diam., while a reversed arrangement required 6.9 to 11.6 diam. Elbows separated by a developing length and randomly arranged yielded an equivalent length range of 3.6 to 10.6 diam. The geometical l/d ratio of the elbows used was 2.05.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 1223-1226 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid phase mass transfer coefficients were measured for the absorption of carbon dioxide into water in concurrent flow. Liquid flow rates ranged up to 300 kg-mol/min. m2 or about 60,000 lb./hr. ft.2. In comparison with countercurrent flow, the coefficients were lower by as much as a factor of 3 with significant gas rate effect. Correlations for concurrent coefficients with liquid and gas flow rates were obtained in the form kxa = CLrGs for 19.0-mm Berl saddles and 6.35-mm and 12.7-mm Rashig rings.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1716-1720 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Chabazite zeolites are used at Oak Ridge National Laboratory to decontaminate wastewaters containing 90Sr and 137Cs. Treatability studies show that chabazite can remove trace amounts of these nuclides from wastewaters containing much higher concentrations of calcium and magnesium. The design of ion-exchange columns for multicomponent systems requires a method for predicting multicomponent equilibria from binary, ternary and quaternary experiments, since the number of experiments required for an empirical equilibrium model is not generally feasible. Binary interaction parameters for the Wilson equation are used to predict solid-phase activity coefficients for the five-component system. The sum of squares of deviations between experimental and predicted solution concentrations for the data points available is calculated. The average deviation per data point for the five-component system is lower than for some of the ternary-and four-component data sets containing calcium or magnesium.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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