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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 7769-7774 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Mixtures of neon or helium with alkali vapor were excited using an argon ion beam. The emission continua observed in the vacuum ultraviolet region between 60 and 80 nm are assigned to the decay of the ionic excimers He+K, He+Na, He+Li, Ne+Rb, Ne+K, Ne+Na, and Ne+Li into the ground state consisting of a rare gas atom and an alkali ion. The binding energies of these excimers range between 0.46 and 0.85 eV. The obtained decay energies and the fine structure splittings agree with the predictions by calculations using phenomenological potentials and by ab initio calculations. Intense emission due to the inner shell excitation of K and Rb is also observed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 3325-3332 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Ionic rare gas alkali excimers Rg+A were produced by exciting Rg/A mixtures in a buffer gas atmosphere by means of an ion or electron beam. As a representative candidate the formation of Kr+K decaying at 135 nm was investigated. The rate constant k(He) for the main reaction Kr++K→Kr+K was determined varying the buffer gas density [He] between 1017 and 1020 cm−3. Values between k(He)=1×10−11 and 5×10−10 cm3 s−1 were observed. At high buffer gas densities the quantum yield ηq for the emission of the 135 nm radiation depends on the ratio [K]/[Kr]. At the optimum value, [K]/[Kr]=0.06, an absolute yield of ηq=1.5% was obtained. Up to a deposited energy of 3 mJ/cm3 the quantum yield is independent on the excitation density. For neon as buffer gas the rate constants k(Ne) are smaller by about a factor of 3, while the efficiency is only slightly less than for He. Kr+K is split into five fine structure states. The quenching of these states by krypton and buffer gas causes the low quantum yield.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Mixtures of rare gases with alkali-metal vapour were excited by a high power argon ion beam in a windowless gas target system. Narrow emission continua were observed in the vacuum ultraviolet region between 60 and 200 nm. The observed emission was assigned to the decay of a new class of excited ionic molecules Rg+ A formed by the combination of a rare gas ion Rg+ with an alkali atom A. These excimer-like ions are of great interest for possible short-wavelength lasers, because the ground state consisting of a rare gas atom and an alkali ion is only weakly bound. The observed decay energies and fine structure splittings agree well with the prediction of calculations. A summary of previous results is presented.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 11 (1988), S. 141-145 
    ISSN: 1434-6079
    Keywords: 33.20.Ni
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Mixtures of rare-gases (Rg) and alkali vapors (A) were excited by helium and argon ions. VUV transitions observed between 131.1 nm and 189.9 nm were ascribed to the decay of (RgA)+ ions where Rg=Kr, Xe and A=Cs, Rb, K, Na, Li. In the (ArA)+ systems (A=Rb, K, Na, Li) transitions appeared between 114.1 nm and 124.7 nm. Since the final state is only weakly bound, the (RgA)+ ions seem to be promising candidates for storage media of VUV lasers.
    Type of Medium: Electronic Resource
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