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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Environmental science & technology 8 (1974), S. 441-444 
    ISSN: 1520-5851
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 13 (1974), S. 1-6 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 206-213 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The adiabatic, evaporating, two-phase flow of steam and water in horizontal pipe including the critical flow was successfully described by a system of nonlinear differential equations which include different phase velocities, fluid acceleration, wall shear forces, interface shear forces, and mass and energy transfer between the phases. The solution of the differential equations by the method of Runge-Kutta was facilitated with a high-speed digital computer. Experimental data were obtained which included void fraction measurement by X-ray attenuation and showed that the theoretical equations described the complex flow phenomena to ± 10% when radial temperature gradients were small. Design charts based on the numerical solution of the theoretical equations are presented for rapid evaluation of the flow variables for the system steam-water including critical flow for inlet pressures from 30 to 150 lb./sq.in.abs., mass flow rates per unit area from 300 to 1,000 lb./sq. ft. sec., and L/D ratios from 25 to 1,000. The critical flow is defined as the maximum flow rate for a given pressure at the point of initial vaporization and L/D ratio.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 701-702 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 698-705 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A 17-reaction mechanism model was postulated to describe the alkylation of isobutane with propylene using sulfuric acid as the catalyst. The scheme was based on the Schmerling carbonium ion mechanism with modifications introduced to account to iC9 and iC10 formation. Solving the steady state rate equations for the rate constants a set of 17 equations of the form ki = f(rcj, rC k, …)/g (Ci, Ck, …) were obtained. Experimental measurements were made in an ideally mixed, continuous-flow stirred-tank reactor, and the necessary data were obtained to compute the rate constants from 65°F to 135°F. The reaction model was found to be valid in the range of 81°F to 135°F using a 95% sulfuric acid catalyst since the rate constants obeyed the Arrhenius theory. The results obtained at 65°F and 95% sulfuric acid showed significant departure from the model. This was possibly due to a change in reaction mechanism. There was an apparent change in selectivity of the catalyst when the concentration was lowered to 90% sulfuric acid. This resulted in increased rates of formation of iC9's and iC10's and decreased rates of formation of iC5's, iC6's and iC8's.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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