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  • 1
    Electronic Resource
    Electronic Resource
    Gas phase electronic spectrum of C3H in the visible (2001)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 6913-6919 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The electronic spectrum of C3H has been observed by means of a resonant two color two photon ionization technique sampling a supersonic plasma source. On the basis of ab initio calculations, vibrational and rotational analysis, the complex vibronic system observed in the visible and near UV is assigned to three electronic transitions, A˜ 2A′←X 2Π, B˜ 2A″←X 2Π and C˜ 2A″←X 2Π of C3H. Potential curves along the CCH bending coordinate have been obtained because of its role for the electronic spectrum and dynamics of C3H. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.1404391
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Photodetachment spectroscopy of the C2nH− (n=2–4) anions in the vicinity of their electron detachment threshold (2002)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 6126-6131 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The electronic spectra of the C2nH(D)−, n=2–4, anions have been observed in the gas phase using photodetachment spectroscopy. These are assigned to 1Π←X 1Σ+ electronic transitions. The 1Π excited states possess a dipole bound character indicated by the energetic proximity between the origin of the transitions and electron affinities. The dipole bound states are related to the X 2Π ground states of C6H and C8H whereas for C4H, which has an X 2Σ+ ground state, the 2Π is an excited state. Vibronic coupling through a bending motion of the carbon skeleton is inferred to be the reason of the stabilization of this state. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.1451248
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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