ISSN:
1434-193X
Schlagwort(e):
Fluorine
;
vic-Difluorination
;
Fluoroalkenes
;
Xenon difluoride
;
Alkenes
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Vic-Difluorination proceeds by the reaction of fluoroalkenes with xenon difluoride to afford the corresponding fluorinated compounds. From the reaction with polyfluoroalkenes, the products are obtained in high to excellent yields. In this reaction, the fluorine atom substituent of alkene stabilizes the cation intermediate and suppresses side-reactions such as rearrangement.
Zusätzliches Material:
2 Tab.
Materialart:
Digitale Medien
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