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  • 1
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 2670-2672 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Electron-nuclear double resonance (ENDOR) has been used to identify the singly ionized zinc vacancy (VZn− center) in ZnGeP2. This S=1/2; defect is the dominant paramagnetic acceptor in the material, and it is associated with the absorption from 0.7 to 2.5 μm that limits the use of ZnGeP2 in optical parametric oscillators. The unpaired spin of the VZn− center is shared nearly equally by two phosphorus nuclei adjacent to the vacancy with little overlap of the wave function onto the other two phosphorus neighbors. Angular dependence of the ENDOR spectrum shows that the two primary 31P nuclei have nearly axial hyperfine matrices with unique axes pointing approximately toward the center of the vacancy. The internuclear axis for these two phosphorus makes an angle of 37.8° with the basal plane. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Electron paramagnetic resonance (EPR) has been used to investigate an acceptor in as-grown single crystals of ZnGeP2. The spectra are characterized by equally spaced triplets with 1:2:1 intensity ratios representing hyperfine interactions (varying from 35 to 55 G in magnitude) with two equivalent phosphorous nuclei. Their angular dependence shows that there are four crystallographically equivalent orientations of the defect. The principal values of the g matrix are 2.002, 2.021, and 2.074 and the corresponding principal axes, at one of the four sites, are the [011], [1¯00], and [01¯1] directions, respectively. Two possible models are suggested for this acceptor: Either a zinc vacancy (VZn) or a zinc ion on a germanium site (ZnGe). It also is suggested that the acceptor responsible for the EPR signal is the same acceptor, namely AL1, that gives rise to a dominant near-infrared absorption band.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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