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  • 1
    Electronic Resource
    Electronic Resource
    Heptacoordinate Rhenium(III)-Bis(terpyridine) Complexes: Syntheses, Characterizations, and Crystal Structures of[Re(terpyridine)2X]2+ (X = OH, Cl, NCS). Substitution Kinetics of [Re(terpyridine)2OH]2+ (1994)
    s.l. : American Chemical Society
    Inorganic chemistry 33 (1994), S. 3442-3451 
    Details
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ic00094a003
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Kupfer - ein “modernes” Bioelement (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 108 (1996), S. 47-64 
    Details
    ISSN: 0044-8249
    Keywords: Bioanorganische Chemie ; Enzyme ; Kupferproteine ; Sauerstoffmetabolismus ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kupfer ist ein bioessentielles Element, das in den beiden relevanten Oxidationsstufen I und II einzigartige chemische Eigenschaften aufweist. Biochemische, molekularbiologische und medizinische Erkenntnisse einerseits sowie die Synthese und Untersuchung niedermolekularer “Modell”-Komplexverbindungen andererseits haben in den letzten Jahren zu wesentlichen Fortschritten bei der Erforschung der teilweise überraschenden Biochemie dieses Spurenelements geführt. Auffallend, jedoch aufgrund des chemischen und des vermuteten evolutionsgeschichtlichen Hintergrundes nachvollziehbar, sind die Funktionen von proteingebundenem Kupfer vor allem im Metabolismus von O2 und N/O-Verbindungen (NO2-, N2O) sowie seine häufige Assoziation mit oxidierenden organischen und anorganischen Radikalen wie etwa Tyrosyl, Semichinonen, Superoxid-Ionen oder Nitrosyl-Radikalen.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19961080105
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  • 3
    Electronic Resource
    Electronic Resource
    Copper - A “Modern” Bioelement (1996)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 35 (1996), S. 43-60 
    Details
    ISSN: 0570-0833
    Keywords: bioinorganic chemistry ; copper proteins ; enzymes ; oxygen metabolism ; radicals ; Bioinorganic chemistry ; Copper proteins ; Enzymes ; Oxygen metabolism ; Radicals ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copper is a bioessential element in biology with truly unique chemical characteristics in its two relevant oxidation states +I and +II. Significant progress has been made in recent years in the elucidation of the frequently surprising biochemistry of this trace element. Those advances were especially furthered through mutual stimulation involving results from biochemistry, molecular biology, and medicine on one hand and the synthesis as well as the structural and spectroscopic characterization of low molecular weight model complexes on the other. The most notable features of protein-bound active copper are its almost exclusive function in the metabolism of O2 or N/O compounds (NO2-, N2O) and its frequent association with oxidizing organic and inorganic radicals such as tyrosyl, semiquinones, superoxide, or nitrosyl. This unique biological role of copper can be rationalized given its chemical and assumed evolutionary background.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.199600431
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    Paper (German National Licenses)
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