ISSN:
0947-3440
Schlagwort(e):
Halogen addition
;
Autoxidation
;
Redox chemistry
;
Oxetes, stable
;
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Small Rings, 88. - Reactions of Tetra-tert-butyltetrahedrane: Oxidation to the Radical Cation as the First StepThe chemistry of tetrahedrane 1 and cyclobutadiene 3 is governed by the initial formation of radical cation 2. In spite of the high steric hindrance 2 cannot be isolated as a radical-ion pair. Reaction of 3 with O2 generates the oxete 21 which is surprisingly stable (up to 200°C).
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/jlac.199519950122
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