ISSN:
1434-4475
Keywords:
Thiomorpholines
;
synthesis
;
reactivity
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A new synthesis of thiomorpholine by ring closure of β-chloro-β′-aminodiethylene-sulfide with potassium hydroxide is reported. Numerous reactions of thiomorpholine (1) and, especially, 2-methyl-3-ethyl-thiomorpholine (2) are described such as acylation, diacylation (3–43), reactions with sulfonic acid chlorides (44–52), isocyanates (53–61, 70–75), diisocyanates (62–66, 76–78) and isothiocyanates (67–69, 79–82), alkylation reactions (83–111) and the synthesis of thiomorpholino-dithiocarbamates (112–121).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00906671
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