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  • 1
    ISSN: 0935-6304
    Keywords: Headspace solid-phase microextraction (HS/SPME) ; capillary gas chromatography ; volatile wine aroma compounds ; aromatic pattern ; chemometric classification ; HS/SPME standard addition method ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Headspace solid-phase microextraction (HS/SPME) was studied and optimized for the capillary gas chromatographic (CGC) analysis of wine aroma compounds. The results were compared with those obtained using the direct sampling mode (DI/SPME) and using liquid/liquid extraction with Kaltron. The aromatic patterns obtained by HS/SPME-CGC were applied to the chemometric classification of wine varieties. The HS/SPME-CGC standard additional method is an appropriate technique for the quantitative analysis of volatile wine aroma compounds.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 19 (1996), S. 257-262 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Solid-phase microextraction ; Food analysis ; Wine bouquet ; Monoterpenes ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The extraction, identification, and quantification of wine aroma compounds are preliminary steps required for further investigation of wine quality, i.e. determination of the varieties of grapes used, the production process, and the origin and age of the wine. This paper deals with the optimization of solid-phase microextraction for the determination of compounds which produce wine bouquet. Optimum operating conditions have been determined to obtain high reproducibility at low cost and with low time-consumption. Several factors influencing the equilibrium of the aroma compounds between the sample and the fiber must be taken into account, including length of contact time between the two phases involved, speed of agitation of the sample, the matrix in which the process takes place, and, furthermore, the place, duration, and temperature of desorption in the injector of the chromatograph.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0935-6304
    Keywords: Solid Phase microextration (SPME) ; Capillary gas chromatography ; Nature of fibers ; Wine aroma compounds ; Terpene profile ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The extraction of wine bouquet components with solid-phase microextraction (SPME) using different fibers was studied. Polyacrylate fibers (PA-85) achieve the most complete bouquet profiles. About ninety substances were identified by capillary gas chromatography-MS and their retention factors were calculated to allow peak identification in capillary-GC-FID chromatograms. The terpene profiles of different wines were recorded by SPME (PA-85)-CGC-FID.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0935-6304
    Keywords: Solid phase microextraction (SPME) ; capillary gas chromatography ; detection limits ; wine aroma compounds ; classification of wines ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Headspace-SPME followed by capillary gas chromatography/mass spectrometry was used to investigate 90 German wines originating from different grape varieties, vintages, and growing areas. Aromagrams obtained in single ion monitoring (SIM) and in the full scan detection mode (SCAN) of quadrupole mass spectrometer were compared. Detection limits, reproducibility, and linearity for some aroma relevant substances were estimated over a wide concentration range. The advantages of SIM data set (lower detection limit, better reproducibility and linearity in the smaller concentration ranges) should be reflected in more reliable results in classification of wines. To verify these expectation, classification of variety by discriminant analysis was performed with cross validation using both SIM and SCAN data sets including 19 aroma compounds, respectively.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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